26623-59-6

Basic information

• Product Name: trans-1,4,5,6,7,7-Hexachlor-bicyclo<2.2.1>hept-5-en-2,3-dicarbonsaeure
• CAS NO: 26623-59-6
• Molecular Weight: 388.846
• Mol File: 26623-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-1,4,5,6,7,7-Hexachlor-bicyclo<2.2.1>hept-5-en-2,3-dicarbonsaeure(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1,4,5,6,7,7-Hexachlor-bicyclo<2.2.1>hept-5-en-2,3-dicarbonsaeure(26623-59-6)
• EPA Substance Registry System: trans-1,4,5,6,7,7-Hexachlor-bicyclo<2.2.1>hept-5-en-2,3-dicarbonsaeure(26623-59-6)

Safety Data

• Hazardous Substances Data: 26623-59-6(Hazardous Substances Data)

Upstream product

• 115-27-5 4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione 

Relevant articles and documents

Phase transfer catalysis by tetraethylammonium bromide: Nucleophilic opening of anhydrides using potassium superoxide in aprotic medium

Tetraethylammonium superoxide, generated in situ by the phase transfer reaction of potassium superoxide and tetraethylammonium bromide, brings about a clean cleavage of various anhydrides, particularly those with high molecular weight in dry dimethylformamide. As an outcome, succinic anhydride 1; glutaric anhydride 2; 3,3-dimethylglutaric anhydride 3; phthalic anhydride 4; diphenic anhydride 5; 1,2,3,4-tetrahydro-9-oxo-1,4-ethanonaphthalene-2,3- endo-dicarboxylic anhydride 6: 1,4,5,6,7,7-hexachloro-5-norbomene-2,3- dicarboxylic anhydride 7; endo-bicyclo [2.2.1] heptan-2-one-5,6-dicarboxylic anhydride 8; cis-5-norbornene-endo-2,3-dicarboxylic anhydride 9 and trans- 1,2-cyclohexane dicarboxylic anhydride 10 have been transformed into their corresponding dicarboxylic acids in fairly good yields. The report demonstrates the applicability of tetraethylammonium bromide as a phase transfer catalyst for efficient superoxide studies.