26741-30-0Relevant articles and documents
Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-elimination reaction
N?tre, Jér?me Le,Scott, Elinor L.,Franssen, Maurice C. R.,Sanders, Johan P. M.
, p. 3712 - 3715 (2010)
Trialkylamines were used as additives in the decarbonylation-elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation.
PROCESS FOR PRODUCTION OF OLEFIN
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, (2011/06/23)
The present invention provides a process for producing an olefin from a carboxylic acid having a β-hydrogen atom or a derivative thereof using the compound containing iodine and at least one metal elements selected from the group consisting of Groups 6, 7, 8, 9, 10 and 11 metals as a catalyst.