26823-15-4Relevant articles and documents
A method of synthesizing chiral alkene propyl alcohol
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Paragraph 0109-0117, (2019/07/04)
The invention discloses a method for synthesizing chiral alkene propyl alcohol method, which belongs to the technical field of organic chemistry. The method adopts the [...] derived binaphthol potassium salt as a chiral [...] catalyst, catalytic [...] pro
Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins
Kohno, Yasushi,Narasaka, Koichi
, p. 322 - 329 (2007/10/02)
The oxidation of α-tributylstannyl alkanoates with tetrabutylammonium hexanitratocerate(IV) generates α-radicals of the alkanoates by eliminating the stannylium ion.The thus-formed radicals react with various electron-rich olefinic compounds, such as silyl enol ethers, giving addition products in good yield.This method formally achieves selective cross coupling between alkanoates and ketones.
A NOVEL METHOD FOR CYCLOPENTANONE ANNULATION. THE USE OF 1-(2-KETOALKYL)CYCLOPROPANOLS TO OBTAIN CYCLOPENTANONES.
Carey, James T.,Helquist, Paul
, p. 1243 - 1246 (2007/10/02)
The condensation of alkyl-substituted thermodynamic enolates with ethyl bromomagnesium cyclopropanone hemiacetal (a cyclopropanone equivalent) provides 1-(2-ketoalkyl)cyclopropanols which in turn are converted into 3-hydroxycyclopentanones by treatment wi