26928-23-4

Basic information

• Product Name: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-
• CAS NO: 26928-23-4
• Molecular Formula: C8H6ClF
• Molecular Weight: 156.587
• Mol File: 26928-23-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(26928-23-4)
• EPA Substance Registry System: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(26928-23-4)

Safety Data

• Hazardous Substances Data: 26928-23-4(Hazardous Substances Data)

Upstream product

• 88691-45-6 (E)-[2-(4-chlorophenyl)ethenyl]trimethylsilane 
• 28321-09-7 1-chloro-4-(2,2-difluorovinyl)benzene 
• 201230-82-2 carbon monoxide 
• 413614-15-0 1-bromo-1-fluoro-2-(4-chlorophenyl)ethylene 
• 104-88-1 4-chlorobenzaldehyde 
• 98509-03-6 1-((E)-2-Benzenesulfonyl-2-fluoro-vinyl)-4-chloro-benzene 
• 98506-75-3 2-Benzenesulfonyl-1-(4-chloro-phenyl)-2-fluoro-ethanol 

Downstream Products

• 1657-50-7 (E)-1-(4-chlorophenyl)-2-phenylethene 
• 73350-59-1 (E)-1-chloro-4-(hex-1-en-1-yl)benzene 
• 223919-54-8 2-[(E)-2-(4-chlorophenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Stereodivergent hydrodefluorination of: Gem -difluoroalkenes: Selective synthesis of (Z)- and (E)-monofluoroalkenes

We have developed a novel approach for the stereodivergent hydrodefluorination of gem-difluoroalkenes using copper(i) catalysts to obtain stereodefined monofluoroalkenes. Both (Z)- and (E)-terminal monofluoroalkenes were obtained by the hydrodefluorination of gem-difluoroalkenes in the presence of copper(i) catalysts and diboron or hydrosilane, respectively, with high stereoselectivity. DFT calculations were conducted to elucidate the stereoselectivity.

Acceleration of alkenyltrimethylsilane fluorination under mild conditions using ultrasound

Alkenyltrimethylsilanes are selectively fluorodesilated to alkenyl fluoride very readily by reaction with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2,2,2]octane bis-tetrafluoroborate (Selectfluor) and N-fluorobenzensulfonimids at room temperature under

A Novel and Efficient Synthesis of Fluoromethyl Phenyl Sulphone and Its Use as a Fluoromethyl Wittig Equivalent

A new synthesis of fluoromethyl phenyl sulphone (2) and the reaction of its conjugate base (3) with carbonyl compounds provides β-fluoro-alcohols (5), which are utilized to prepare terminal vinyl fluorides (8) via α-fluoro-α,β-unsaturated sulphones (6).