2715-43-7

Basic information

• Product Name: 4-VINYL-BENZOIC ACID ETHYL ESTER
• Synonyms: ETHYL 4-VINYLBENZOATE;4-VINYL-BENZOIC ACID ETHYL ESTER;Benzoic acid, 4-ethenyl-, ethyl ester;4-ethenyl-Benzoic acid ethyl ester
• CAS NO: 2715-43-7
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21
• Product Categories: Aromatic Esters
• Mol File: 2715-43-7.mol
• Article Data: 40

Chemical Properties

• Boiling Point: 270.1°C at 760 mmHg
• Flash Point: 122.5°C
• Appearance: /
• Density: 1.037g/cm³
• Vapor Pressure: 0.00696mmHg at 25°C
• Refractive Index: 1.543
• CAS DataBase Reference: 4-VINYL-BENZOIC ACID ETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 4-VINYL-BENZOIC ACID ETHYL ESTER(2715-43-7)
• EPA Substance Registry System: 4-VINYL-BENZOIC ACID ETHYL ESTER(2715-43-7)

Safety Data

• Hazardous Substances Data: 2715-43-7(Hazardous Substances Data)

Usage

General Description

4-Vinyl-benzoic acid ethyl ester, also known as ethyl 4-vinylbenzoate, is a chemical compound with the molecular formula C11H12O2. It is mainly used as a monomer in the production of polymers and as a precursor in the synthesis of various pharmaceuticals and fine chemicals. 4-Vinyl-benzoic acid ethyl ester is a clear, colorless to pale yellow liquid with a pungent odor and is slightly soluble in water but soluble in organic solvents. It is important to handle this chemical with care as it may cause irritation to the eyes and skin upon contact, and inhalation of its vapors may cause respiratory irritation.

InChI:InChI=1/C11H12O2/c1-3-9-5-7-10(8-6-9)11(12)13-4-2/h3,5-8H,1,4H2,2H3

Upstream product

• 348-06-1 p-carboethoxybenzenediazonium tetrafluoroborate 
• 94-09-7 p-aminoethylbenzoate 
• 78-08-0 Triethoxyvinylsilane 
• 5798-75-4 Ethyl 4-bromobenzoate 
• 64-17-5 ethanol 
• 1076-96-6 methyl 4-vinylbenzoate 
• 79-10-7 acrylic acid 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 92988-08-4 trivinylboroxin 
• 2768-02-7 (vinyl)trimethoxylsilane 
• 637-69-4 4-Methoxystyrene 
• 125261-30-5 p-(ethoxycarbonyl)phenyl triflate 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 188889-20-5 ethyl (E)-4-[2-(5,6,7,8-tetrahydro-5,5-dimethyl-8-oxo-2-naphthalenyl)ethenyl]-benzoate 
• 201141-33-5 ethyl(E)-4-[2-(5,6-dihydro-5,5-dimethyl-8-(phenylthio)-naphthalen-2-yl)ethenyl]benzoate 
• 201141-37-9 ethyl (E)-4-[-2-(5,6-dihydro-5,5-dimethyl-8-(ethylthio)-naphthalen-2-yl)ethenyl]benzoate 
• 201141-42-6 ethyl (E)-4-[2-(5,6-tetrahydro-5,5-dimethyl-8-(propyliden-2-yl)-naphthalen-2-yl)ethenyl]-benzoate 
• 35391-85-6 4-cyclopropyl-benzoic acid ethyl ester 
• 1446446-53-2 C₂₇H₃₄BNO₃ 
• 1446446-65-6 ethyl 4-((1E,3E)-6-acetoxy-3-phenyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexa-1,3-dienyl)benzoate 
• 1446757-97-6 (E,E)-2,5-dimethoxy-1,4-bis[2-(4-(ethyl carboxylate)styryl)]benzene 
• 1451497-61-2 C₁₆H₂₄O₃Si 
• 1451498-96-6 C₂₆H₃₄O₅Si₂ 
• 1152-30-3 (E)-ethyl 4-styrylbenzoate 

Relevant articles and documents

Synthesis, structure and characterization of two solvatochromic metal-organic frameworks for chemical-sensing applications

Two isostructural Zr and Hf metal-organic frameworks (PU-1 and PU-2) were constructed from a hitherto unreported anthracene-derived dicarboxylate ligand and inorganic [M6O4(OH)4(CO2)12] (M = Zr4+ or Hf4+) secondary building unit under solvothermal conditions. They crystallized in the cubic Fd3m space group with doubly interpenetrated fcu-c topology. PU-1 exhibited an eye-catching color change within different solvents (especially in water) and could be a solvatochromic sensing material for recognition of solvent molecules.

Highly selective electroreductive linear dimerization of electron-deficient vinylarenes

A direct electroreductive dimerization of electron-deficient vinylarenes for the synthesis of 1,4-diarylbutane has been developed using a simple undivided cell with inexpensive carbon electrodes at room temperature. The control and deuterium-labeling experiments of electroreductive dimerization suggest that the hydrogen source comes from the solvent CH3CN. This protocol provides a mild and efficient route for the construction of C–C bond in moderate to good yields with high regioselectivity and broad substrate scope.

Nickel-Catalyzed Ligand-Free Hiyama Coupling of Aryl Bromides and Vinyltrimethoxysilane

We herein disclose the first Ni-catalyzed Hiyama coupling of aryl halides with vinylsilanes. This protocol uses cheap, nontoxic, and stable vinyltrimethoxysilane as the vinyl donor, proceeds under mild and ligand-free conditions, furnishing a diverse variety of styrene derivatives in high yields with excellent functional group compatibility.