271600-23-8

Basic information

• Product Name: [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester
• Synonyms: [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester
• CAS NO: 271600-23-8
• Molecular Weight: 542.19
• Mol File: 271600-23-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester(271600-23-8)
• EPA Substance Registry System: [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester(271600-23-8)

Safety Data

• Hazardous Substances Data: 271600-23-8(Hazardous Substances Data)

Upstream product

• 204577-67-3 (1R)-2-endo-acetyl-2-exo-(trimethylsilyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane 

Downstream Products

• 479064-93-2 (R)-3-(4-chlorophenyl)-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid 

Relevant articles and documents

α-Oxymethyl ketone enolates for the asymmetric Mannich reaction. From acetylene and N-alkoxycarbonylimines to β-amino acids

The insufficient diastereoselectivity and generality, which are the main problems of the 'acetate' aza - aldol reaction, can now be addressed through the reaction of the lithium enolate of endo-O-trimethylsilyl acetyl isoborneol with various N[(p-tolylsul