272-30-0Relevant articles and documents
Thermal reactions of organyl chalcogenides with α,β-unsaturated aldehydes
Deryagina, E. N.,Korchevin, N. A.,Shilkina, T. A.,Sukhomazova, E. N.,Levanova, E. P.
, p. 447 - 450 (2007/10/03)
Thermalgas-phase reactions of acrolein, cinnamaldehyde, and benzaldehyde with diorganyl chalcogenides and diorganyl dichalcogenides were studied.Acrolein does not react with chalcogenides at 300-600 deg C but completely decomposes under reaction conditions.At 600-650 deg C, cinnamaldehyde reacts only with diorganyl selenides and diselenides to give benzoselenophene.Its highest yield (53percent) is achieved in the reaction with dimethyl diselenide at 630 deg C and at an equimolar ratio of the reactants.The gas-phase reactions of benzaldehyde at 400-500 deg C afford chalcogen-containing derivatives of several types, among which thioanisole and its selenium or tellurium analogs predominate.The mechanisms of the above reactions were discussed in terms of homolytic substitution of the formyl group at unsaturated carbon atoms by chalcogenyl radicals. - Keywords: gas-phase reactions; cinnamaldehyde; benzaldehyde; chalcogenyl radicals; benzoselenophene, selenoanisole, telluroanisole.
HIGH-TEMPERATURE ORGANIC SYNTHESIS XLIII. REACTIONS OF ORGANIC DISELENIDES WITH PROPARGYL ALCOHOL
Deryagina, E. N.,Korchevin, N. A.,Voronkov, M. G.
, p. 1069 - 1072 (2007/10/02)
The gas-phase reaction of propargyl alcohol with dialkyl diselenides at 400 - 430 deg C leads to a high yield of 1,2-diselenol-3-one. 1,2-Diselenol-3-one is formed in a similar way from diphenyl diselenide at 450 - 500 deg C but with a low yield.The mechanism of the thermal dissociation of the diselenides and their reactions with propargyl alcohol is discussed.
