2720-41-4

Basic information

• Product Name: Cyclohexane-1-thione
• Synonyms: Cyclohexane-1-thione;Cyclohexanethione
• CAS NO: 2720-41-4
• Molecular Formula: C₆H₁₀S
• Molecular Weight: 114.2086
• Mol File: 2720-41-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 138.6°C (estimate)
• Appearance: /
• Density: 0.941 (estimate)
• Refractive Index: 1.5375
• CAS DataBase Reference: Cyclohexane-1-thione(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane-1-thione(2720-41-4)
• EPA Substance Registry System: Cyclohexane-1-thione(2720-41-4)

Safety Data

• Hazardous Substances Data: 2720-41-4(Hazardous Substances Data)

Usage

General Description

Cyclohexane-1-thione, also known as thiomorpholine or thiacyclohexane, is a chemical compound with the formula C6H11SH. It is a colorless liquid with a foul odor that is used as a solvent and in the production of rubber chemicals and pharmaceuticals. Cyclohexane-1-thione is also a versatile building block in organic chemistry, serving as a thiolating agent in various reactions. It is a highly reactive compound due to its thiol group, allowing it to participate in a wide range of chemical reactions, including nucleophilic substitution and addition reactions. However, it should be handled with caution due to its potential toxicity and irritant properties.

Upstream product

• 108-94-1 cyclohexanone 
• 7647-01-0 hydrogenchloride 
• 64-17-5 ethanol 
• 7783-06-4 hydrogen sulfide 
• 108878-62-2 S-cyclohexyl cyclohexane-1-sulfinothioate 
• 179-01-1 3,3,5,5-bis(pentamethylene)-1,2,4-trithiolane 
• 1132-38-3 N-cyclohexylidenebenzenamine 

Downstream Products

• 15786-82-0 thioacetic acid S-cyclohex-1-enyl ester 
• 1589-61-3 cyclohexanone semicarbazone 
• 4410-13-3 1-(methylthio)cyclohexene 
• 55499-39-3 diethyl (1-mercaptocyclohexyl)phosphonate 
• 55499-41-7 diisopropyl (1-mercaptocyclohexyl)phosphonate 
• 83236-49-1 4-phenyl-3-cyano-5,6-tetramethylenepyridine-2<1H>-thione 
• 15786-77-3 1-[(2-hydroxy)ethylthioxy]cyclohexane 
• 15869-70-2 2,4,7,-Trithia-3,3-pentamethylen-octan-2,2,4,4,7,7-hexoxyd 
• 15786-89-7 <2-Hydroxy-cyclohexyl>-cyclohexen-(1)-yl-sulfid 
• 10321-25-2 2,6-di(p-nitrobenzylidene)cyclohexanone 
• 15786-98-8 4-NItro-benzaldehyd-di-cyclohexen-⁽¹⁾-yl-mercaptal 
• 15786-85-3 Diphenylthiolessigsaeure-cyclohexen-⁽¹⁾-ylester 
• 1132-38-3 N-cyclohexylidenebenzenamine 
• 15869-68-8 1-Mercapto-1-ethylmercapto-cyclohexan 

Relevant articles and documents

π-Face-selective hetero Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide. An excellent trapping reagent for thioaldehydes and thioketones

Hetero Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide (1) with thioaldehydes and thioketones take place exclusively, except the reaction with thiobenzophenone, at the syn-π-face of 1 with respect to the S=O bond. The π-face selectivity was ex

Gas Phase Reactions, 24. The Thermal Generation of Thiocarbonyl Compounds

Thiocarbonyl derivatives R1R2C=S with R1, R2 = H, CH3, C6H5 can be generated thermally in the gas phase from a variety of precursors.Especially advantageous are the cleavage of propene from allyl sulfides or, for their preparation in pure form, the pyrolysis of dithietane or trithiolane derivatives.Photoelectron spectroscopy proves to be well-suited for gas analysis in the flow tube used, for the optimization of the decomposition conditions, and via assignment of the observed ionization patterns for the characterization of the thioaldehydes and thioketones prepared.