27318-90-7

Basic information

• Product Name: 1 10-PHENANTHROLINE-5 6-DIONE 97
• Synonyms: 1 10-PHENANTHROLINE-5 6-DIONE 97;1,10-Phenanthroline-5,6-quinone;1,10-Phenanthroline-5,6-dione;phen-5,6-dione;5,6-dihydro-1,10-phenanthroline-5,6-dione;5,6-Dihydro-5,6-dioxo-1,10-phenanthroline;Phenanthroline-5,6-;1,10-Phenanthroline-5,6-dione 97%
• CAS NO: 27318-90-7
• Molecular Formula: C₁₂H₆N₂O₂
• Molecular Weight: 210.19
• Product Categories: Electronic Chemicals;C11 to C12;Carbonyl Compounds;Ketones
• Mol File: 27318-90-7.mol
• Article Data: 11

Chemical Properties

• Melting Point: 260 °C (dec.)(lit.)
• Boiling Point: 456.1 °C at 760 mmHg
• Flash Point: 229.1 °C
• Appearance: /
• Density: 1.444 g/cm³
• Vapor Pressure: 1.66E-08mmHg at 25°C
• Refractive Index: 1.677
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 0.26±0.20(Predicted)
• Water Solubility: Insoluble in water.
• CAS DataBase Reference: 1 10-PHENANTHROLINE-5 6-DIONE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 1 10-PHENANTHROLINE-5 6-DIONE 97(27318-90-7)
• EPA Substance Registry System: 1 10-PHENANTHROLINE-5 6-DIONE 97(27318-90-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 27318-90-7(Hazardous Substances Data)

Usage

Chemical Properties

Yellow solid

Uses

Different sources of media describe the Uses of 27318-90-7 differently. You can refer to the following data:
1. A Bifunctional quinone oxidant
2. 1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

General Description

1,10-Phenanthroline-5,6-dione (phendio) forms Cu(II) and Ag(I) phendio complexes, which show potent anti-fungal and anti-cancer activity. The modification of glassy carbon (GC) electrodes with phendio complexes of transition metals leads to the catalytic oxidation of NADH at low overpotential.

InChI:InChI=1/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 97919-82-9 5,6-dihydro-1,10-phenanthroline 
• 484-17-3 9-Phenanthrol 
• 68527-66-2 6-chloro-8-nitroquinoline 
• 89-63-4 4-Chloro-2-nitroaniline 
• 4199-89-7 5-Chloro-1,10-phenanthroline 
• 5470-75-7 8-amino-6-chloroquinoline 
• 65115-91-5 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline 
• 142009-79-8 trans-5-anilino-6-hydroxy-5,6-dihydro-1,10-phenanthroline 
• 5144-89-8 1,10-phenanthroline hydrate 
• 168646-53-5 5-nitro-6-amino-1,10-phenanthroline 
• 168646-54-6 1,10-o-phenanthroline-5,6-diamine 
• 113492-23-2 5,6-methylenedioxy-1,10-phenanthroline 
• 7664-93-9 sulfuric acid 

Downstream Products

• 1055875-10-9 [Cd(5-bromoisophthalate)(4,5-diazafluoren-9-one)]n 
• 1056148-54-9 [Cd(5-bromoisophthalate)(1,10-phenanthroline-5,6-dione)]n 
• 1485413-28-2 2-ethoxy-6-(1H-imidazol[4,5-f][1,10]phenanthroline-2-yl)phenol 
• 1445166-46-0 2-(4-hydroxy-3-ethoxyphenyl)-1H-imidazo[4,5-f][1,10](phenanthroline) 
• 1414972-41-0 2-(4-(benzyloxy)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 
• 935696-55-2 2-(4-(benzyloxy)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 
• 215601-94-8 2-(3-chlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 
• 614717-91-8 2-(3-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 
• 1397576-24-7 1-(4-tolyl)-2-phenyl-1H-imidazo[4,5-f] [1,10]phenanthroline 
• 1403355-88-3 4-(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenyl)morpholine 
• 1333335-12-8 2-(3,4,5-trimethoxyphenyl)imidazo[4,5-f]-1,10-phenanthroline 
• 1382969-54-1 C₁₉H₁₁BrN₄O 
• 1384983-93-0 2-(2,4-difluorophenyl)-1-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline 
• 446241-98-1 4-(dipyrido[3,2-a:2^,,3^,-c]phenazin-11-yl)benzene-1,2-diamine 

Relevant articles and documents

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Eu-MOFs with 2-(4-carboxyphenyl)imidazo[4,5-f]-1,10-phenanthrolineand ditopic carboxylates as coligands: Synthesis, structure, high thermostability, and luminescence properties

(Graph Presented) Hydrothermal reactions of europium(III) salt with 2-(4-carboxyphenyl)imidazo[4,5- f ]-1,10-phenanthroline and dicarboxylic acid as coligands - benzene-1,4-dicarboxylic acid, 4,4′-biphenyldicarboxylic acid, 2,5-dibromoterephthalic acid, and naphthalene-1,4-dicarboxylic acid - lead to four europium fluorescent materials (1-4). Structural analyses reveal that 1 - 4 have binuclear 3D metal - organic frameworks with different channels, void volumes, and conjugated structures tuned by ditopic carboxylates. There are no latticed and coordinated water molecules occurring in 1 - 3, while the free water molecules fill in 1D channels of 4. 4′ was readily obtained via water removal of 4. Thermal analyses of all compounds show the high thermal stability of the main framework up to 450 °C. Optical studies indicate that 1 - 4 and 4′ show the characteristic red luminescence emission of the EuIII ion in the visible regions at room temperature. On the basis of emission spectra, their luminescence lifetimes were determined. In particular, compound 4??? shows a longer lifetime (τ = 0.942 ms) and significantly enhanced quantum yield (39%) compared with those of 1 (11%, 0.770 ms), 2 (4%, 0.414 ms), 3 (18%, 0.807 ms), and 4 (26%, 0.858 ms).

Hydrothermal syntheses, crystal structures, and photophysical properties of two coordination polymers with mixed ligands

Two novel metal-organic coordination polymers [Cd(ipdt)(m-BDC)·3H2O]n (1) and [Pb(mip)2(NTC) ·2H2O]n (2) [ipdt = 2,6-Dimethoxy-4-(1H-1,3,7,8-tetraaza-cyclopenta[l]phenanthren-2-yl)-phenol, mip = 2-(3-

COMPLEX COMPRISING A RARE-EARTH METAL ION AND A COMPLEXING MOIETY

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