275825-05-3

Basic information

• Product Name: (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone
• Synonyms: (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone
• CAS NO: 275825-05-3
• Molecular Weight: 194.317
• Mol File: 275825-05-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone(275825-05-3)
• EPA Substance Registry System: (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone(275825-05-3)

Safety Data

• Hazardous Substances Data: 275825-05-3(Hazardous Substances Data)

Upstream product

• 7770-41-4 1-methyl-2-oxocyclohexanecarboxylic acid 2-propenyl ester 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 
• 86950-89-2 allyl (2-methylcyclohex-1-en-1-yl)carbonate 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 812639-07-9 (2S)-2-methyl-2-(2-propen-1-yl)cyclohexanone 
• 60733-10-0 (S)-seudenol 
• 1344731-00-5 5-(1-methylcyclohex-2-en-1-yl)pent-1-en-3-ol 
• 1344731-15-2 (2S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanol 
• 1344731-02-7 (2R)-2-methyl-2-(4-methylpent-4-en-1-yl)-7-oxabicyclo[4.1.0]heptanes 
• 1344731-01-6 2-methyl-5-((S)-1-methylcyclohex-2-en-1-yl)pent-1-en-3-yl acetate 
• 275825-09-7 (S)-6-methyl-6-(4-methylbenzenesulfonyloxypropyl)-1,4-dioxaspiro[4.5]decane 
• 275825-11-1 3-((S)-6-Methyl-1,4-dioxa-spiro[4.5]dec-6-yl)-propionic acid methyl ester 
• 275825-04-2 (S)-6-(3-iodopropyl)-6-methyl-1,4-dioxaspiro[4.5]decane 
• 171737-76-1 (S)-2-methyl-2-(3-hydroxypropyl)cyclohexanone ethylene ketal 

Downstream Products

• 275825-13-3 Toluene-4-sulfonic acid (1R,2R,5S,8aR)-1,2,5-trimethyl-5-(4-methyl-pent-4-enyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-ylmethyl ester 
• 275825-12-2 C₁₅H₂₆O 
• 275825-03-1 (S)-6-methyl-6-(4-methylpent-4-en-1-yl)-1-vinylcyclohex-1-ene 

Relevant articles and documents

Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation

Pd-catalyzed enantioselective alkylation in conjunction with further synthetic elaboration enables the formal total syntheses of a number of "classic" natural product target molecules. This publication highlights recent methods for setting quaternary and tetrasubstituted tertiary carbon stereocenters to address the synthetic hurdles encountered over many decades across multiple compound classes spanning carbohydrate derivatives, terpenes, and alkaloids. These enantioselective methods will impact both academic and industrial settings, where the synthesis of stereogenic quaternary carbons is a continuing challenge.

Concise asymmetric synthesis of dysidiolide

The cdc25A protein phosphatase inhibitor dysidiolide (1) has been synthesized via intermolecular Diels-Alder reaction of the triene 4 with crotonaldehyde and construction of a quaternary carbon center by methylation of the exocyclic enolate. (C) 2000 Elsevier Science Ltd.