2759-56-0

Basic information

• Product Name: 4-(prop-1-en-2-yl)phenyl acetate
• Synonyms: 4-(Prop-1-en-2-yl)phenyl acetate; phenol, 4-(1-methylethenyl)-, acetate
• CAS NO: 2759-56-0
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.2118
• Mol File: 2759-56-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 257.172°C at 760 mmHg
• Flash Point: 97.182°C
• Density: 1.019g/cm³
• Vapor Pressure: 0.015mmHg at 25°C
• Refractive Index: 1.511
• CAS DataBase Reference: 4-(prop-1-en-2-yl)phenyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(prop-1-en-2-yl)phenyl acetate(2759-56-0)
• EPA Substance Registry System: 4-(prop-1-en-2-yl)phenyl acetate(2759-56-0)

Safety Data

• Hazardous Substances Data: 2759-56-0(Hazardous Substances Data)

Upstream product

• 2948-47-2 2-(4-hydroxyphenyl)-2-propanol 
• 108-24-7 acetic anhydride 
• 108-22-5 Isopropenyl acetate 
• 1927-95-3 4-bromophenyl acetate 
• 876-27-7 4-chlorophenyl acetate 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 74-88-4 methyl iodide 
• 13031-43-1 4-acetyloxyacetophenone 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 63721-02-8 p-Acetoxycumylchlorid 
• 75-89-8 2,2,2-trifluoroethanol 
• 75-90-1 2,2,2-Trifluoroacetaldehyde 
• 13031-43-1 4-acetyloxyacetophenone 

Relevant articles and documents

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method includes the steps of: (A) providing a compound (I) with an unsaturated double bond, a trifluoromethyl-containing reagent, and a catalyst; wherein, the catalyst is represented by Formula (II): M(O)mL1yL2z??(II);wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and(B) mixing the compound with an unsaturated double bond and the trifluoromethyl-containing reagent to perform an oxidative cleavage of the compound with the unsaturated double bond by using the catalyst in air or under oxygen atmosphere condition to obtain a compound represented by Formula (III):

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method comprises the following step: (A) providing a compound (I) with an unsaturated double bond, a reagent with trifluoromethyl, and a catalyst; wherein the catalyst is represented by the following formula (II): M(O)mL1yL2z (II); wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and (B) mixing the compound with an unsaturated double bond and the reagent with a trifluoromethyl to perform an oxidation of the compound with the unsaturated double bond by using the catalyst at air or an oxygen condition to get a compound presented as formula (III):

Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.