27675-38-3

Basic information

• Product Name: 3-METHYL-1-NITROBUT-1-ENE
• Synonyms: 3-METHYL-1-NITROBUT-1-ENE;1-Butene, 3-methyl-1-nitro-, (1E)-
• CAS NO: 27675-38-3
• Molecular Formula: C₅H₉NO₂
• Molecular Weight: 115.13
• Mol File: 27675-38-3.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 160.157°C at 760 mmHg
• Flash Point: 49.826°C
• Appearance: /
• Density: 0.977g/cm³
• Vapor Pressure: 3.143mmHg at 25°C
• Refractive Index: 1.443
• CAS DataBase Reference: 3-METHYL-1-NITROBUT-1-ENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHYL-1-NITROBUT-1-ENE(27675-38-3)
• EPA Substance Registry System: 3-METHYL-1-NITROBUT-1-ENE(27675-38-3)

Safety Data

• Hazardous Substances Data: 27675-38-3(Hazardous Substances Data)

Usage

General Description

3-Methyl-1-nitrobut-1-ene is a chemical compound with the molecular formula C5H9NO2. It is a highly reactive and volatile liquid with a pale yellow color and a fruity, pungent odor. 3-METHYL-1-NITROBUT-1-ENE is primarily used as an intermediate in the manufacturing of various pharmaceuticals and agrochemicals, as well as in the production of rubber and plastic additives. Due to its highly flammable nature and potential health hazards, such as irritation to the respiratory system and skin, proper handling and storage precautions are necessary when working with 3-methyl-1-nitrobut-1-ene.

InChI:InChI=1/C5H9NO2/c1-5(2)3-4-6(7)8/h3-5H,1-2H3/b4-3+

Upstream product

• 75-52-5 nitromethane 
• 78-84-2 isobutyraldehyde 
• 141377-55-1 3-methyl-1-nitrobutan-2-ol 
• 41367-90-2 3-methyl-1-nitrobutan-2-yl acetate 
• 71-43-2 benzene 
• 1809-65-0 3-methyl-1-nitrobut-2-ene 

Downstream Products

• 185426-03-3 (1S,2R,1'R)-(-)-N-<1-methyl-2-(2'-methyl-1'-nitromethylpropoxy)-2-phenylethyl>formamide 

Relevant articles and documents

Effect of the α-alkyl substituent of conjugated nitroolefins on the formation of cyclic nitronic esters vs. nitrocyclopropanes in their reaction with sulfur ylides

The formation of cyclic nitronic esters (isoxazoline N-oxides) vs. nitrocyclopropanes in the reaction of conjugated nitroolefins with sulfur ylides depends on the presence of an α-alkyl substituent in the conjugated nitroolefins.

A Nickel-Bisdiamine Porous Organic Polymer as Heterogeneous Chiral Catalyst for Asymmetric Michael Addition to Aliphatic Nitroalkenes

We report a polystyrene-incorporated chiral nickel(II)-bisdiamine complex, which is accessible on gram-scale. This metal complex functions as a heterogeneous catalyst for the enantioselective Michael addition between malonates and aliphatic nitroalkenes,

CuI-Catalysed Enantioselective Alkyl 1,4-Additions to (E)-Nitroalkenes and Cyclic Enones with Phosphino-Oxazoline Ligands

Catalytic enantioselective conjugate additions of simple alkyl groups to nitroalkenes or cyclic enones that result in the formation of tertiary C–C bonds are described. For these stereoselective addition reactions, new chiral phosphino-oxazoline ligands w