277-06-5

Basic information

• Product Name: DIEPOXYCYCLOHEXANE
• Synonyms: DIEPOXYCYCLOHEXANE;1,2,3,4-DIEPOXYCYCLOHEXANE;3,8-DIOXATRICYCLO-OCTANE;CYCLOHEXA-1,3-DIENEDIOXIDE;TRANS-1,2,3,4-DIEPOXYCYCLOHEXANE;(1R)-1β,2β:3β,4β-Diepoxycyclohexane
• CAS NO: 277-06-5
• Molecular Formula: C₆H₈O₂
• Molecular Weight: 112.14
• Mol File: 277-06-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 147.55°C (rough estimate)
• Flash Point: 75.2°C
• Appearance: /
• Density: 1.0494 (rough estimate)
• Vapor Pressure: 0.319mmHg at 25°C
• Refractive Index: 1.4792 (estimate)
• CAS DataBase Reference: DIEPOXYCYCLOHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: DIEPOXYCYCLOHEXANE(277-06-5)
• EPA Substance Registry System: DIEPOXYCYCLOHEXANE(277-06-5)

Safety Data

• Hazardous Substances Data: 277-06-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H8O2/c1-2-4-6(8-4)5-3(1)7-5/h3-6H,1-2H2

Upstream product

• 1165952-91-9 cyclohexa-1,3-diene 
• 6705-51-7 3,4-epoxycyclohexene 

Downstream Products

• 20089-18-3 cyclohexanetetrol-(1r,2t,3t,4c) 
• 2975-92-0 (+/-)-1L-cyclohexane-1,3/2,4-tetrol 
• 1091615-48-3 (1R(S),2R(S),3S(R),4S(R))-2,3-dihydroxycyclo-hexane-1,4-diyl dinitrate 
• 18422-07-6 (+/-)-1r.2t.3c.4t-tetrabenzoyloxy-cyclohexane 
• 909728-81-0 1r.2t.3t.4c-tetrabenzoyloxy-cyclohexane 

Relevant articles and documents

Regioselective Cleavage of Electron-Rich Double Bonds in Dienes to Carbonyl Compounds with [Fe(OTf)2(mix-BPBP)] and a Combination of H2O2 and NaIO4

A method for the regioselective transformation of dienes to carbonyl compounds has been developed. Electron-rich olefins react selectively to yield valuable aldehydes and ketones. The method is based on the catalyst [Fe(OTf)2(mix-BPBP)] with an oxidant combination of H2O2 (1.0 equiv.) and NaIO4 (1.5 equiv.); it uses mild conditions and short reaction times, and it outperforms other olefin cleavage methodologies. The combination of an Fe-based catalyst, [Fe(OTf)2(mix-BPBP)], and the oxidants H2O2 and NaIO4 can discriminate between electronically different double bonds and oxidatively cleave the electron-rich bond in dienes to yield aldehydes and ketones in a regioselective manner. The reaction requires mild conditions (0-50 C) and short reaction times (70 min).