27798-45-4

Basic information

• Product Name: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE
• Synonyms: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE
• CAS NO: 27798-45-4
• Molecular Formula: C₁₃H₁₈
• Molecular Weight: 174.28
• Mol File: 27798-45-4.mol
• Article Data: 27

Chemical Properties

• Boiling Point: 105°C 10,5mm
• Flash Point: 86.7°C
• Appearance: /
• Density: 0.869g/cm³
• Vapor Pressure: 0.103mmHg at 25°C
• Refractive Index: 1.495
• CAS DataBase Reference: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(27798-45-4)
• EPA Substance Registry System: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(27798-45-4)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 27798-45-4(Hazardous Substances Data)

Usage

General Description

3-(4-tert-butylphenyl)-1-propene is a chemical compound with the formula C13H18. It is an organic compound classified as an alkene, which contains a benzene ring with a tert-butyl group attached to the fourth carbon atom and a propene group attached to the first carbon atom. 3-(4-TERT-BUTYLPHENYL)-1-PROPENE is used in the production of polymers and plastics, as well as in the synthesis of other organic compounds. It is also used as a reagent in organic chemistry reactions and as a precursor to various other chemicals. It is important to handle this chemical with care and in accordance with safety guidelines, as it can be hazardous if not handled properly.

InChI:InChI=1/C13H18/c1-5-6-11-7-9-12(10-8-11)13(2,3)4/h5,7-10H,1,6H2,2-4H3

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 106-95-6 allyl bromide 
• 253185-03-4 tert-butylbenzene 
• 762-72-1 allyl-trimethyl-silane 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 173604-95-0 CH₂CHCH₂SnBr(N(Si(CH₃)3)2)2 
• 123324-71-0 p-tert-butylphenylboronic acid 
• 98-54-4 para-tert-butylphenol 
• 4873-09-0 allyl tosylate 
• 591-87-7 Allyl acetate 
• 10152-76-8 allylmethyl sulfide 
• 1092390-58-3 sodium 1,1-dimethyl-1-(2-propen-1-yl)silanolate 
• 154318-75-9 4-tert-butylphenyl triflate 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 1265015-19-7 (E)-3-(4-tert-butylphenyl)acrylic acid n-butyl ester 
• 80-54-6 lilial 
• 1024039-12-0 2-(4-tert-butylphenyl)butyraldehyde 
• 62518-66-5 3-(4-tert-butylphenyl)propionaldehyde 
• 211314-96-4 2-(4-(tert-butyl)phenyl)butanoic acid 
• 66735-04-4 4-(1,1-dimethylethyl)-α-methyl-benzenepropanoic acid 
• 24475-36-3 4-[4-(1,1-dimethylethyl)phenyl]butanoic acid 
• 117721-77-4 (E)-3-(4-(tert-butyl)phenyl)prop-2-en-1-ol 
• 1375536-67-6 (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 917114-13-7 2-(4-(tert-butyl)phenyl)quinoline 
• 1613403-39-6 (2E,4E)-methyl 5-(4-(tert-butyl)phenyl)-2-phenylpenta-2,4-dienoate 

Relevant articles and documents

Manganese catalyzed dehydrogenative silylation of alkenes: Direct access to allylsilanes

Dehydrogenative silylation of alkenes with silanes to produce allylsilanes is achieved through manganese catalysis with a wide scope of substrate tolerance. This transformation involves silane radicals initiated by manganese complex without additional oxidant additives. It offers a general, convenient and practical protocol with excellent functional group compatibility and gram-scale capacity for the modular synthesis of allylsilanes.

Palladium-Catalyzed Oxidative Allylation of Sulfoxonium Ylides: Regioselective Synthesis of Conjugated Dienones

The first examples of palladium-catalyzed allylic C-H oxidative allylation of sulfoxonium ylides to afford the corresponding conjugated dienones with moderate to good yields have been established. The features of this novel conversion include mild reaction conditions, wide substrate scope, and excellent regioselectivity.

Carbonylative Transformation of Allylarenes with CO Surrogates: Tunable Synthesis of 4-Arylbutanoic Acids, 2-Arylbutanoic Acids, and 4-Arylbutanals

In this Communication, procedures for the selective synthesis of 4-arylbutanoic acids, 2-arylbutanoic acids, and 4-arylbutanals from the same allylbenzenes have been developed. With formic acid or TFBen as the CO surrogate, reactions proceed selectively and effectively under carbon monoxide gas-free conditions.