2808-86-8Relevant articles and documents
Resourceful treatment method of picloram solid residues
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Paragraph 0059-0064, (2020/11/23)
The invention relates to a picloram solid residue resourceful treatment method which comprises the following steps: a) carrying out decarboxylation reaction on picloram solid residues, performing filtering, taking filtrate, and separating out solid; b) sequentially carrying out diazotization and chlorination reaction on the solid obtained in the step a), separating out the solid, performing filtering, taking a filter cake, and performing separating to obtain 2, 3, 4, 5-tetrachloropyridine; c) subjecting the 2, 3, 4, 5-tetrachloropyridine obtained in the step b) to a dechlorination reaction soas to obtain 2, 3, 5-trichloropyridine and/or 2, 5-dichloropyridine. According to the resourceful treatment method provided by the invention, the picloram solid residues can be converted into 2, 3, 5-trichloropyridine products with good market demand prospects and relatively high economic values, and further efficient utilization of the picloram solid residues is realized.
DESTRUCTIVE CHLORINATION OF 3,4,5-TRICHLORO-2-(TRICHLOROMETHYL)PYRIDINE
Emel'yanov, V. I.,Stul', B. Ya.,Korolev, B. M.
, p. 1168 - 1171 (2007/10/02)
The extensive destructive chlorination of 3,4,5-trichloro-2-(trichloromethyl)pyridine proceeds by both thermal (160-245 deg C) and photochemical pathways.Perchloropyridine, perchloropicoline, and carbon tetrachloride are formed.The chlorinated derivatives of pyridine are formed by the loss of the CCl3 group with its subsequent replacement by a chlorine atom.