2848-62-6

Basic information

• Product Name: benzyl(trimethyl)germane
• Synonyms: 1-GE-1& 1& 1R [WLN]; 2848-62-6; Germane, trimethyl(phenylmethyl)-; Trimethyl(phenylmethyl)germane
• CAS NO: 2848-62-6
• Molecular Formula: C₁₀H₁₆Ge
• Molecular Weight: 208.874
• Mol File: 2848-62-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 220.7°C at 760 mmHg
• Flash Point: 78.4°C
• Vapor Pressure: 0.165mmHg at 25°C
• CAS DataBase Reference: benzyl(trimethyl)germane(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl(trimethyl)germane(2848-62-6)
• EPA Substance Registry System: benzyl(trimethyl)germane(2848-62-6)

Safety Data

• Hazardous Substances Data: 2848-62-6(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 1529-47-1 chlorotrimethylgermane 
• 4314-94-7 benzyl(trimethyl)tin 
• 6921-34-2 benzylmagnesium chloride 
• 76054-64-3 7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-germanorbornadiene 
• 620-05-3 iodomethylbenzene 
• 90-99-3 diphenylchloromethane 
• 881-42-5 diphenylmethyllithium 
• 1066-37-1 trimethylbromogermane 
• 137482-81-6 benzylpentamethyldigermane 
• 90030-12-9 benzoylbromodimethylgermane 
• 1730-66-1 methylgermanium bromide 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 108-88-3 toluene 

Downstream Products

• 81303-11-9 1-trimethylgermyl-1,1,2-triphenylethane 
• 197807-42-4 (1,2-bis(dimethylamino)ethane-N,N')zinc bis(phenyl(trimethylgermyl)methanide) 

Relevant articles and documents

Reactivity of N-(chlorodimethylgermyl)methyl and N-(chlorodimethylsilyl) methyl derivatives of lactams and amides toward Grignard reagents

N-[(Chlorodimethylgermyl)methyl]lactams and -amides containing a five-coordinate germanium atom react with Grignard reagents chemoselectively by the Ge-Cl bond to form four-coordinate germanium compounds. The method of competitive reactions was used to es

Photochemical Reactions of Vinyl-, Styryl- and Benzyl-Substituted Digermanes

Photochemical reactions of vinyl-, styryl- and benzyl-substituted digermanes by chemical trapping experiments.Photolysis of vinylpentamethyldigermane afforded 1-trimethyl-2-(pentamethyldigermyl)ethane as a major product, and styrylpentamethyldigermanes gave mainly styryltrimethylgermane.On the other hand, photolysis of benzyl-substituted digermanes (benzylpentamethyldigermane and 1,2-dibenzyltetramethyldigermane) gave hydrogermanes and hydrodigermanes as main products, respectively.These products were derived from germyl radicals generated by photoinduced homolysis of the germanium-germanium bond.In carbon tetra chloride (CCl4), these germyl radicals were converted to the corresponding chlorogermanes by abstraction of a chlorine atom.Germylene species were also to be evolved from such photolyses.

1,n-TRIORGANOSILYL MIGRATIONS IN THE REARRANGEMENTS OF SILYL-SUBSTITUTED ORGANOLITHIUM COMPOUNDS

Under the agency of the potent lithiating agent, n-butyllithium in TMEDA, an array of organosilanes was found to undergo 1,n-silyl rearangements via carbanionic intermediates.Unambiguous 1,2-, 1,3- and 1,4-silyl shifts were unconvered in 1-trimethylsilyl-