28598-82-5Relevant articles and documents
Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source
Mizukami, Yuki,Song, Zhiyi,Takahashi, Tamotsu
supporting information, p. 5942 - 5945 (2016/01/09)
The halogen exchange reaction of aliphatic fluorine compounds with organic halides as the halogen source was achieved. Treatment of alkyl fluorides (primary, secondary, or tertiary fluorides) with a catalytic amount of titanocene dihalides, trialkyl aluminum, and polyhalomethanes (chloro or bromo methanes) as the halogen source gave the corresponding alkyl halides in excellent yields under mild conditions. In the case of a fluorine/iodine exchange, no titanocene catalyst is needed. Only C-F bonds are selectively activated under these conditions, whereas alkyl chlorides, bromides, and iodides are tolerant to these reactions.
Lengthening alkyl spacers to increase SBA-15-anchored Rh-P complex activities in 1-octene hydroformylation
Zhou, Wei,He, Dehua
supporting information; experimental part, p. 5839 - 5841 (2009/04/13)
The alkyl spacer was lengthened in heterogenizing a Rh-P complex into mesoporous silicate SBA-15 to increase the immobilized catalyst activities in 1-octene hydroformylation. The Royal Society of Chemistry.
Room-temperature alkyl-alkyl Suzuki cross-coupling of alkyl bromides that possess β hydrogens [1]
Netherton,Dai,Neuschuetz,Fu
, p. 10099 - 10100 (2007/10/03)
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