2917-47-7Relevant articles and documents
Synthesis of 1-silabicyclo[4.4.0]dec-5-en-4-ones: A model of the A and B rings of 10-silatestosterone
Diez-Gonzalez, Silvia,Paugam, Renee,Blanco, Luis
body text, p. 3298 - 3307 (2009/04/07)
1-Silabicyclo[4.4.0]dec-5-en-4-ones, a novel type of organosilicon compound, have been prepared from 2-methylidene-1-(3-oxopropyl)-1- silacyclohexanes by an ene reaction as the key transformation. Various routes to the starting aldehydes from 3-halopropyl, allyl, or 3-(4-methoxybenzyloxy) propylsilanes have been investigated. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
REGIO- AND STEREOSELECTIVE SYNTHESIS OF ALLYLTRIMETHYLSILANES VIA KRIEF-REICH ELIMINATION IN β-SELENO-γ-SILYL ALCOHOLS
Sarkar, Tarun K.,Ghosh, Sunil K.,Satapathi, Tushar K.
, p. 1885 - 1898 (2007/10/02)
The synthesis of (E)-allyltrimethylsilanes by regio- and stereocontrolled pathways is described based on the preference for Krief-Reich elimination over silicon-controlled rearrangement in β-seleno-γ-silyl alcohols, readily available from α-selenoaldehydes, 10 - 12.Usefulness of this protocol for the introduction of the allylsilane function α to the carbonyl group in cycloalkanones as well as for the preparation of unsymmetrically substituted allylsilanes is also reported.
Organoborane-Catalyzed Hydroalumination of Olefins
Maruoka, Keiji,Sano, Hiromi,Shinoda, Kiyotaka,Nakai, Shuichi,Yamamoto, Hisashi
, p. 6036 - 6038 (2007/10/02)
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