2918-18-5

Basic information

• Product Name: SEBACICACID,DIPHENYLESTER
• Synonyms: SEBACICACID,DIPHENYLESTER;DIPHENYLSEBACATE
• CAS NO: 2918-18-5
• Molecular Formula: C₂₂H₂₆O₄
• Molecular Weight: 354.44
• Mol File: 2918-18-5.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: SEBACICACID,DIPHENYLESTER(CAS DataBase Reference)
• NIST Chemistry Reference: SEBACICACID,DIPHENYLESTER(2918-18-5)
• EPA Substance Registry System: SEBACICACID,DIPHENYLESTER(2918-18-5)

Safety Data

• Hazardous Substances Data: 2918-18-5(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 102-09-0 bis(phenyl) carbonate 
• 111-20-6 1,10-decanedioic acid 
• 111-19-3 sebacoyl chloride 

Downstream Products

• 10401-05-5 1,10-bis-(2-hydroxy-phenyl)-decane-1,10-dione 
• 2533-59-7 1,10-bis-(4-hydroxy-phenyl)-decane-1,10-dione 

Relevant articles and documents

Photo-on-Demand Synthesis of Vilsmeier Reagents with Chloroform and Their Applications to One-Pot Organic Syntheses

The Vilsmeier reagent (VR), first reported a century ago, is a versatile reagent in a variety of organic reactions. It is used extensively in formylation reactions. However, the synthesis of VR generally requires highly toxic and corrosive reagents such as POCl3, SOCl2, or COCl2. In this study, we found that VR is readily obtained from a CHCl3 solution containing N,N-dimethylformamide or N,N-dimethylacetamide upon photo-irradiation under O2 bubbling. The corresponding Vilsmeier reagents were obtained in high yields with the generation of gaseous HCl and CO2 as byproducts to allow their isolations as crystalline solid products amenable to analysis by X-ray crystallography. With the advantage of using CHCl3, which bifunctionally serves as a reactant and a solvent, this photo-on-demand VR synthesis is available for one-pot syntheses of aldehydes, acid chlorides, formates, ketones, esters, and amides.

Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

Phenyl esters were obtained in moderate to high yields by reaction of aliphatic and aromatic carboxylic acids with one equivalent of diphenyl carbonate in the presence of catalytic amounts of tertiary amine bases, such as DBU, TBD and DMAP under neat conditions at elevated temperatures (>100°C).