292150-03-9Relevant articles and documents
Enantioselective ring opening of epoxides by fluoride anion promoted by a cooperative dual-catalyst system
Kalow, Julia A.,Doyle, Abigail G.
supporting information; experimental part, p. 3268 - 3269 (2010/05/01)
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Synthesis of optically active vicinal fluorohydrins by lipase-catalyzed deracemization
Woelker, Doerthe,Haufe, Guenter
, p. 3015 - 3021 (2007/10/03)
Three microbial lipases have been used to deracemize trans-2-fluorocycloalkanols 2 both by hydrolysis of the corresponding acetates 3 or chloroacetates 4 and by esterification of the fluorohydrins 2 using vinyl acetate and vinyl chloroacetate, respectivel
Enantioselective ring-opening of epoxides by HF-reagents: Asymmetric synthesis of fluoro lactones
Haufe, Günter,Bruns, Stefan,Runge, Martina
, p. 55 - 61 (2007/10/03)
The asymmetric ring opening of meso- and racemic-epoxides with different HF-reagents mediated by enantiopure (salen)chromium chloride provides optically active fluorohydrins with maximum 90% e.e. This reaction as well as lipase-catalyzed deracemization of