292863-61-7Relevant articles and documents
Novel synthesis of fluoroalkylated α,β-unsaturated ketones by the oxygenative perfluoroalkylation of α-chlorostyrenes
Yoshida, Masato,Ohkoshi, Masanori,Iyoda, Masahiko
, p. 804 - 805 (2000)
The photochemical reaction of perfluoroalkyl iodide with α-chlorostyrenes in the presence of hexabutylditin under oxygen atmosphere produced fluoroalkylated α,β-unsaturated ketones in moderate to good yields.
Copper-Catalyzed Fluoroolefination of Silyl Enol Ethers and Ketones toward the Synthesis of β-Fluoroenones
Li, Yanlin,Liu, Jing,Zhao, Shuang,Du, Xuzhao,Guo, Minjie,Zhao, Wentao,Tang, Xiangyang,Wang, Guangwei
, p. 917 - 920 (2018/02/22)
A general and facile synthetic method for β-fluoroenones from silyl enol ethers or ketones, with a copper-amine catalyst system, has been developed. The reaction proceeded by a tandem process of difluoroalkylation-hydrolysis-dehydrofluorination. This method is characterized by high yields, excellent Z/E ratios, a low-cost catalyst, and a broad substrate scope. The synthetic potential of β-fluoroenones has been demonstrated by the construction of various complicated organofluorine molecules.
Photochemical oxyfluoroalkylation of styrenes by the addition of perfluoroalkyl radicals in an atmosphere of oxygen
Yoshida, Masato,Ohkoshi, Masanori,Aoki, Nobuyuki,Ohnuma, Yuki,Iyoda, Masahiko
, p. 5731 - 5734 (2007/10/03)
The photochemical reaction of perfluoroalkyl iodide with α-methylstyrene and related compounds in the presence of hexabutylditin under oxygen atmosphere produces the fluoroalkylated alcohols in good yields. The reaction was photochemically initiated, and
