295-48-7Relevant articles and documents
Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties
Seemann, Alexandra,Panten, Johannes,Kirschning, Andreas
supporting information, p. 13924 - 13933 (2021/05/29)
Starting from small cyclic ketones, continuous flow synthesis is used to produce medium-sized rings and macrocycles that are relevant for the fragrance industry. Triperoxides are important intermediates in this process and are pyrolyzed at temperatures above 250 °C. The synthesis is carried out in two continuously operated flow reactors connected by a membrane-operated separator. The practicality of flow chemistry is impressively demonstrated in this work by the use of hazardous reagent mixtures (30% H2O2, 65% HNO3) and the pyrolysis of no less problematic peroxides. All new macrocycles were tested for their olfactory properties in relation to musk.
Cyclooctane metathesis catalyzed by silica-supported tungsten pentamethyl [(ΞSiO)W(Me)5]: Distribution of macrocyclic alkanes
Riache, Nassima,Callens, Emmanuel,Samantaray, Manoja K.,Kharbatia, Najeh M.,Atiqullah, Muhammad,Basset, Jean-Marie
supporting information, p. 15089 - 15094 (2015/02/19)
Metathesis of cyclic alkanes catalyzed by the new surface complex [(ΞSiO)W(Me)5] affords a wide distribution of cyclic and macrocyclic alkanes. The major products with the formula CnH2n are the result of either a ring contraction or ring expans
A Tandem Denitration-Deoxygenation of α-Nitro Ketones via (p-Tolylsulfonyl)hydrazones with Lithium Aluminum Hydride: A Practical Synthesis of (Z)-9-Tricosene, the Sex Pheromone of the Housefly (Musca domestica)
Ballini, Roberto,Petrini, Marino,Rosini, Goffredo
, p. 5159 - 5161 (2007/10/02)
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