300830-78-8

Basic information

• Product Name: 2,4-Cyclohexadien-1-ol, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-iodo-, (1R,6R)-rel-
• CAS NO: 300830-78-8
• Molecular Formula: C22H25IO2Si
• Molecular Weight: 476.429
• Mol File: 300830-78-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,4-Cyclohexadien-1-ol, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-iodo-, (1R,6R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Cyclohexadien-1-ol, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-iodo-, (1R,6R)-rel-(300830-78-8)
• EPA Substance Registry System: 2,4-Cyclohexadien-1-ol, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-iodo-, (1R,6R)-rel-(300830-78-8)

Safety Data

• Hazardous Substances Data: 300830-78-8(Hazardous Substances Data)

Upstream product

• 138769-92-3 cis-(1S,2S)-1,2-dihydroxy-3-iodocyclohexa-3,5-diene 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 231934-87-5 (3aR,4R,5S,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,4,5,7a-tetrahydro-6-iodo-2,2-dimethyl-1,3-benzodioxol-5-ol 
• 403986-44-7 (3aR,4R,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,7a-dihydro-6-iodo-2,2-dimethyl-1,3-benzodioxol-5(4H)-one 
• 403986-45-8 (3aR,4R,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,7a-dihydro-2,2,6-trimethyl-1,3-benzodioxol-5(4H)-one 
• 403986-41-4 (1R,2R,3S,4S)-3-(tert-Butyl-diphenyl-silanyloxy)-5-iodo-cyclohex-5-ene-1,2,4-triol 

Relevant articles and documents

Syntheses of the D-aldopentoses from non-carbohydrate sources

The cis-1,2-dihydrocatechols 5-7, which are obtained in high yield and ca. 99.8% ee by microbial oxidation of the corresponding aromatic compound, have been converted, via reaction sequences involving three distinct types of one-carbon deletion processes, into the four D-aldopentoses.