3056-60-8

Basic information

• Product Name: Acetic acid 3-ethylphenyl ester
• Synonyms: 3-Ethylphenol acetate;Acetic acid 3-ethylphenyl ester
• CAS NO: 3056-60-8
• Molecular Formula: C₁₀H₁₂O₂
• Molecular Weight: 164.2011
• Mol File: 3056-60-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 208.4°Cat760mmHg
• Flash Point: 84.4°C
• Appearance: /
• Density: 1.027g/cm³
• Vapor Pressure: 0.215mmHg at 25°C
• Refractive Index: 1.501
• CAS DataBase Reference: Acetic acid 3-ethylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid 3-ethylphenyl ester(3056-60-8)
• EPA Substance Registry System: Acetic acid 3-ethylphenyl ester(3056-60-8)

Safety Data

• Hazardous Substances Data: 3056-60-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12O2/c1-3-9-5-4-6-10(7-9)12-8(2)11/h4-7H,3H2,1-2H3

Upstream product

• 620-17-7 3-ethylphenol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 100-41-4 ethylbenzene 

Downstream Products

• 103323-98-4 1-(2-ethyl-4-hydroxy-phenyl)-ethanone 
• 5896-50-4 1-(4-ethyl-2-hydroxyphenyl)-ethanone 
• 1620-30-0 diphenyl(pyridin-4-yl)methanol 
• 858446-58-9 1-(2-ethoxy-4,5-diethyl-phenyl)-3-chloro-propan-1-one 
• 856073-06-8 3-chloro-1-(4,5-diethyl-2-methoxy-phenyl)-propan-1-one 
• 34681-92-0 acetic acid-(3,4-diethyl-phenyl ester) 
• 858014-49-0 3,4-diethyl-phenetole 
• 73124-56-8 3,4-diethyl-anisole 
• 56394-40-2 1-(4,5-diethyl-2-hydroxy-phenyl)-ethanone 
• 875-85-4 3,4-diethylphenol 
• 2349-70-4 2-ethylhydroquinone 
• 649551-68-8 7-ethyl-3-hydroxy-2-(3,4,5-trimethoxy-phenyl)-chromen-4-one 
• 121-71-1 3-Hydroxyacetophenone 

Relevant articles and documents

Photocarboxylation of Benzylic C-H Bonds

The carboxylation of sp3-hybridized C-H bonds with CO2 is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C-H bonds with CO2 into 2-arylpropionic acids under metal-free conditions. Photo-oxidized triisopropylsilanethiol was used as the hydrogen atom transfer catalyst to afford a benzylic radical that accepts an electron from the reduced form of 2,3,4,6-tetra(9H-carbazol-9-yl)-5-(1-phenylethyl)benzonitrile generated in situ. The resulting benzylic carbanion reacts with CO2 to generate the corresponding carboxylic acid after protonation. The reaction proceeded without the addition of any sacrificial electron donor, electron acceptor or stoichiometric additives. Moderate to good yields of the desired products were obtained in a broad substrate scope. Several drugs were successfully synthesized using the novel strategy.

Chelating Bis-N-heterocyclic Carbene-Palladium(II) Complexes for Oxidative Arene C-H Functionalization

Bis-N-heterocyclic carbene (NHC)-chelated palladium(II) complexes have been synthesized, characterized fully including single-crystal X-ray structural analyses, and utilized for the first time toward catalytic oxidative C-H functionalization of arenes with PhI(OAc)2 and N-bromosuccinimide. (Figure Presented).

Zinc oxide (ZnO) as a new, highly efficient, and reusable catalyst for acylation of alcohols, phenols and amines under solvent free conditions

Zinc oxide (ZnO) is a highly efficient catalyst for the acylation of a variety of alcohols, phenols and amines with acid chlorides or acid anhydrides under solvent free conditions. Primary, secondary, tertiary, allylic and benzylic alcohols, diols and phenols with electron donating or withdrawing substituents can be easily acylated in good to excellent yield.