307-37-9

Basic information

• Product Name: 1H,1H-PERFLUORO-1-DECANOL
• Synonyms: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-NONADECAFLUORO-1-DECANOL;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-NONADECFLUORO-1-DECANOL;1H,1H-PERFLUORO-1-DECANOL 98%;1H,1H-Perfluorodecan-1-ol 98%;1H,1H-Perfluorodecan-1-ol98%;1H,1H-Nonadecafluoro-1-decanol;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Nonadecafluoro-1-decanol,98%;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Nonadecafluorodecan-1-ol, (Perfluoronon-1-yl)methanol
• CAS NO: 307-37-9
• Molecular Formula: C₁₀H₃F₁₉O
• Molecular Weight: 500.1
• EINECS: -0
• Product Categories: Alcohols;C9 to C30;Oxygen Compounds
• Mol File: 307-37-9.mol
• Article Data: 1

Chemical Properties

• Melting Point: 87-90 °C(lit.)
• Boiling Point: 192 °C735 mm Hg(lit.)
• Flash Point: 95°C/20mm
• Appearance: /
• Density: 1.6820 (estimate)
• Vapor Pressure: 0.116mmHg at 25°C
• Refractive Index: 1.285
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• PKA: 12.88±0.10(Predicted)
• BRN: 1810012
• CAS DataBase Reference: 1H,1H-PERFLUORO-1-DECANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1H,1H-PERFLUORO-1-DECANOL(307-37-9)
• EPA Substance Registry System: 1H,1H-PERFLUORO-1-DECANOL(307-37-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 24/25
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 307-37-9(Hazardous Substances Data)

Usage

Chemical Properties

white powder

Uses

1H,1H-Perfluoro-1-decanol can be introduced into esterifying moiety of bacteriochlorophyll c in green sulfur photosynthetic bacterium Chlorobaculum tepidum by pigment biosynthesis.

General Description

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Nonadecafluoro-1-decanol is a fluorotelomer alcohol (FTOH).

InChI:InChI=1/C10H3F19O/c11-2(12,1-30)3(13,14)4(15,16)5(17,18)6(19,20)7(21,22)8(23,24)9(25,26)10(27,28)29/h30H,1H2

Upstream product

• 307-79-9 perfluorodecanoic acid methyl ester 

Downstream Products

• 335-83-1 acrylic acid-(1H,1H-nonadecafluoro-decyl ester) 
• 1474115-45-1 4-[(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluorodecyl)oxy]phthalonitrile 
• 1474115-56-4 4-chloro-5-[(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluorodecyl)oxy]phthalonitrile 
• 1384267-39-3 C₂₂H₁₉F₁₉N₂O 
• 1189024-72-3 (2R,5S)-2-(2',2',3',3',4',4',5',5',6',6',7',7',8',8',9',9',10',10',10'-nonadecafluorodecyloxy)-3-phenyl-1,3-diaza-2-phoshpabicyclo-[3.3.0]octane 
• 1174457-96-5 (2S,5R)-2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluorodecyloxy)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]octane 
• 871014-94-7 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-1-decyl 4-toluenesulfonate 

Relevant articles and documents

A process for the preparation of the fluoro method

The invention relates to a method of preparing fluoroalcohol of which the structure formula is F3C(CF2)nCH2OH, wherein n is an integer of 2-8. The method includes following steps: (I) mixing fluorocarboxylic acid and isopropyl alcohol and performing a temperature-increasing reflux reaction; (II) when the reaction is finished, distilling the reaction liquid to remove generated water and isopropyl alcohol, and cooling the rest reaction liquid to room temperature; (III) pouring the reaction liquid into distillated water, regulating the pH value to 6.5-7 by an alkali liquid, allowing the reaction liquid to stand to layer the reaction liquid to obtain an organic layer; (IV) removing water from the organic layer to obtain fluorocarboxylic isopropyl ester; (V) adding the fluorocarboxylic isopropyl ester and a solvent into a high-pressure reaction kettle with addition of a hydrogenation catalyst and a co-catalyst, sealing the reaction kettle, increasing the temperature and filling hydrogen to a high pressure for performing a reaction for 20-60 h; (VI) when the reaction is finished, cooling the reaction kettle to room temperature, discharging hydrogen to obtain a reaction mixed liquid; (VII) performing rectification to the reaction mixed liquid to separate the solvent, cooling the rest liquid and pouring the rest liquid into distillated water and regulating the pH value to 6.5-7 by an acid liquid; and (VIII) allowing the mixed liquid to stand to layer the mixed liquid to obtain an organic layer, removing water from the organic layer and distilling the organic layer to obtain the corresponding fluoroalcohol.