30718-17-3 Usage
Uses
(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.
General Description
Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products.
Check Digit Verification of cas no
The CAS Registry Mumber 30718-17-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,0,7,1 and 8 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 30718-17:
(7*3)+(6*0)+(5*7)+(4*1)+(3*8)+(2*1)+(1*7)=93
93 % 10 = 3
So 30718-17-3 is a valid CAS Registry Number.
InChI:InChI=1/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
30718-17-3Relevant articles and documents
-
West,R.,Gornowicz,G.A.
, p. 385 - 388 (1970)
-
Process for the synthesis of imidazoles
-
Page/Page column 5, (2008/06/13)
The present invention provides a process for the preparation of imidazoles by reacting a cyano compound with a silylalkylisocyanide compound. Such imidazoles are useful pharmacologically-active compounds and/or intermediates for the preparation of pharmacologically-active compounds.
Alkaloid synthesis via the intramolecular imidate methylide 1,3-dipolar cycloaddition reaction
Smith, Richard,Livinghouse, Tom
, p. 3559 - 3568 (2007/10/02)
A concise synthesis for the neurotoxic physostigmine alkaloid d,l-eserethole is described which relys upon an intramolecular cycloaddition reaction involving a "non-stabilized" imidate methylide and an unactivated alkene. The facility of this cyclization
