309269-73-6

Basic information

• Product Name: S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol
• Synonyms: S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol;(S)-BIMBOL;(S)-2,2'-Dihydroxy-α,α,α',α'-tetraphenyl-[1,1'- binaphthalene]-3,3'-dimethanol, 99%e.e.;(S)-2,2'-Dihydroxy-α;'-tetraphenyl-[1,1'-binaphthalene]-3,3'-dimethanol, 98% (99% ee)
• CAS NO: 309269-73-6
• Molecular Formula: C46H34O4
• Molecular Weight: 650.77
• Mol File: 309269-73-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 820.1±65.0 °C(Predicted)
• Appearance: /
• Density: 1.297±0.06 g/cm3(Predicted)
• PKA: 8.20±0.50(Predicted)
• CAS DataBase Reference: S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol(CAS DataBase Reference)
• NIST Chemistry Reference: S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol(309269-73-6)
• EPA Substance Registry System: S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol(309269-73-6)

Safety Data

• Hazardous Substances Data: 309269-73-6(Hazardous Substances Data)

Usage

General Description

S-2,2'-dihydroxy-α,α,α',α'-tetraphenyl-[1,1'-Binaphthalene]-3,3'-diMethanol is a compound with a complex chemical structure consisting of two naphthalene rings connected by a central carbon atom. It contains four phenyl groups and two hydroxyl groups attached to the naphthalene rings. This chemical compound is used in the synthesis of chiral ligands and catalysis, particularly in asymmetric synthesis. Its unique structure and properties make it a valuable tool in the field of organic chemistry and chemical research.

Upstream product

• 602-09-5 1,1'-bi-2-naphthol 
• 173831-50-0 rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene 
• 263744-23-6 Dimethyl 2,2'-bis(methoxymethoxy)-1,1'-binaphthalene-3,3'-dicarboxylate 
• 18531-92-5 (S)-2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylic acid 
• 100-58-3 phenylmagnesium bromide 
• 74292-20-9 (S)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl 
• 55426-75-0 3-(hydroxydiphenylmethyl)naphthalen-2-ol 
• 18531-94-7 (R)-1,1'-Bi-2-naphthol 

Relevant articles and documents

Synthesis, characterization and application of some axially chiral binaphthyl phosphoric acids in asymmetric mannich reaction

Two novel chiral Bronsted acids 3b and 3c were prepared without involving the complexity of Suzuki coupling. Catalyst 3c bearing two additional hydroxyl groups at 3 and 3′ positions of axially chiral 1,1-binaphthalene-2,2′-diol phosphoric acid was applied

Enantioselective br?nsted acid catalyzed addition reactions of methyleneaminopyrrolidine to imines

A new series of BINOL-derived multidentate Br?nsted acid catalysts has been developed for the enantioselective addition of the d 1-synthon, methyleneaminopyrrolidine, to N-Boc imines, yielding the versatile, protected α-aminohydrazone intermedi

Synthesis of new bifunctional BINOL derivatives

A series of new 3,3′-disubstituted BINOL derivatives have been synthesised. In a preliminary study, the asymmetric induction of these ligands was investigated in the addition of diethyl zinc to benzaldehyde in the absence of Ti(Oi-Pr)4. This showed different enantioselectivity and activity from those of the unsubstituted BINOL.