3096-62-6

Basic information

• Product Name: N-hydroxy-2,3-dimethylaniline
• Synonyms: benzenamine, N-hydroxy-2,3-dimethyl-; N-Hydroxy-2,3-dimethylaniline
• CAS NO: 3096-62-6
• Molecular Formula: C₈H₁₁NO
• Molecular Weight: 137.179
• Mol File: 3096-62-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 243.9°C at 760 mmHg
• Flash Point: 111.7°C
• Density: 1.12g/cm³
• Vapor Pressure: 0.0168mmHg at 25°C
• Refractive Index: 1.609
• PKA: 9.03±0.70(Predicted)
• CAS DataBase Reference: N-hydroxy-2,3-dimethylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-hydroxy-2,3-dimethylaniline(3096-62-6)
• EPA Substance Registry System: N-hydroxy-2,3-dimethylaniline(3096-62-6)

Safety Data

• Hazardous Substances Data: 3096-62-6(Hazardous Substances Data)

Upstream product

• 83-41-0 2,3-dimethylnitrobenzene 

Downstream Products

• 19618-11-2 bis-(2,3-dimethyl-phenyl)-diazene-N-oxide 
• 59478-05-6 3,3-dimethyl-1-(2,3-dimethylphenyl)triazene-1-oxide 
• 69891-38-9 N-(2,3-dimethylphenyl)-N-hydroxycinnamamide 
• 107418-14-4 bis(2,3-dimethyl)phenylhydrazine 
• 29418-34-6 bis-(2,3-dimethyl-phenyl)-diazene 
• 17075-25-1 1,4-dimethyl-2-nitrosobenzene 
• 87-59-2 2,3-Dimethylaniline 
• 3096-69-3 4-amino-2,3-dimethylphenol 
• 227008-56-2 1,2-dimethyl-3-nitrosobenzene 
• 83-41-0 2,3-dimethylnitrobenzene 

Relevant articles and documents

Redox-Neutral Selenium-Catalysed Isomerisation of para-Hydroxamic Acids into para-Aminophenols

A selenium-catalysed para-hydroxylation of N-aryl-hydroxamic acids is reported. Mechanistically, the reaction comprises an N?O bond cleavage and consecutive selenium-induced [2,3]-rearrangement to deliver para-hydroxyaniline derivatives. The mechanism is studied through both 18O-crossover experiments as well as quantum chemical calculations. This redox-neutral transformation provides an unconventional synthetic approach to para-aminophenols.

Synthesis of meta-substituted anilines via copper-catalyzed [1,3]-methoxy rearrangement

meta-Substituted anilines were efficiently synthesized via copper-catalyzed [1,3]-methoxy rearrangement of N-methoxyanilines followed by Michael addition of nucleophiles to the in situ generated ortho-quinol imine. The present reaction exhibits excellent

Regioselective installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds for the construction of: Para-amino-arylfluorosulfates

The construction of para-amino-arylfluorosulfates was achieved through installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds by the reaction of N-arylhydroxylamine with sulfuryl fluoride (SO2Fs