3164-13-4

Basic information

• Product Name: 2-(4-BROMO-PHENYL)-BENZOOXAZOLE
• Synonyms: CHEMBRDG-BB 4010236;2-(4-BROMO-PHENYL)-BENZOOXAZOLE;2-(4-bromophenyl)-1,3-benzoxazole(SALTDATA: FREE);2-(4-Bromophenyl)-1,3-benzoxazole;2-(p-Bromophenyl)benzoxazole;Benzoxazole,2-(4-bromophenyl)-
• CAS NO: 3164-13-4
• Molecular Formula: C₁₃H₈BrNO
• Molecular Weight: 274.11272
• Mol File: 3164-13-4.mol
• Article Data: 123

Chemical Properties

• Melting Point: 158-159℃
• Boiling Point: 339℃
• Flash Point: 159℃
• Appearance: /
• Density: 1.514
• Vapor Pressure: 0.000185mmHg at 25°C
• Refractive Index: 1.659
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Toluene
• PKA: 0.88±0.10(Predicted)
• CAS DataBase Reference: 2-(4-BROMO-PHENYL)-BENZOOXAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-BROMO-PHENYL)-BENZOOXAZOLE(3164-13-4)
• EPA Substance Registry System: 2-(4-BROMO-PHENYL)-BENZOOXAZOLE(3164-13-4)

Safety Data

• Hazardous Substances Data: 3164-13-4(Hazardous Substances Data)

Usage

Physical Form

Solid

Uses

2-(4-Bromo-Phenyl)-Benzooxazole (cas# 3164-13-4) is a useful research chemical.

InChI:InChI=1/C13H8BrNO/c14-10-7-5-9(6-8-10)13-15-11-3-1-2-4-12(11)16-13/h1-8H

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 
• 95-55-6 2-amino-phenol 
• 698-67-9 p-bromobenzamide 
• 117649-27-1 2-(4-bromo-benzylidenamino)-phenol 
• 586-76-5 4-Bromobenzoic acid 
• 586-75-4 4-chlorobenzoyl chloride 
• 313268-56-3 C₁₃H₉BrClNO 
• 273-53-0 benzoxazole 
• 201230-82-2 carbon monoxide 
• 589-87-7 1,4-bromoiodobenzene 
• 34176-08-4 sodium 4-bromobenzenesulfinate 
• 873-75-6 4-bromobenzenemethanol 
• 88-75-5 2-hydroxynitrobenzene 
• 41018-52-4 (4-bromophenyl)-λ³-iodanediyl diacetate 

Downstream Products

• 833-50-1 2-phenylbenzo[d]oxazole 
• 109113-66-8 2-[4-phenylethynyl]phenylbenzoxazole 
• 225100-55-0 5-<4-(2-benzoxazolyl)phenyl>ethynyl-2'-deoxyuridine 
• 215451-97-1 3',5'-O-diacetyl-5-<4-(2-benzoxazolyl)phenyl>ethynyl-2'-deoxyuridine 
• 225100-57-2 5'-O-(4,4'-dimethoxytrityl)-5-<4-(benzoxazolyl)phenyl>ethynyl-2'-deoxyuridine 
• 439090-73-0 (2-(benzo[d]oxazol-2-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1159445-47-2 4-(benzoxazol-2-yl)-4'-(3-phenylquinoxalin-2-yl)triphenylamine 
• 1271754-01-8 C₄₅H₂₉N₃O₂ 
• 1196685-64-9 2,2'-[2,2'-bipyridine-5,6-diylbis(biphenyl-4,4'-diyl)]bisbenzoxazole 
• 1196685-66-1 2,2'-[2,3'-bipyridine-5,6-diylbis(biphenyl-4,4'-diyl)]bisbenzoxazole 
• 1196685-69-4 2,2'-[2,4'-bipyridine-5,6-diylbis(biphenyl-4,4'-diyl)]bisbenzoxazole 
• 1196685-73-0 2,2'-[2-(bipyridin-2-yl)pyridine-5,6-diylbis(biphenyl-4,4'-diyl)]bisbenzoxazole 
• 17064-45-8 2-(4-biphenylyl)benzoxazole 
• 49743-93-3 (4'-methyl[biphenyl]-4-yl)benzo[d]oxazole 

Relevant articles and documents

Tertiary amine derivatives and organic electroluminescent device including the same

A UV-region high-energy external light source is effectively absorbed to minimize damage to organic materials in the organic electroluminescent device. 1 Is a cross-sectional view of an organic electroluminescence device according to the present invention. O-2 electrode 1 Or more organic material layers disposed between the (2) and (1) th electrodes. A capping layer is included. The organic material layer and/or the capping layer may include the 1 st amine derivative represented by Formula 3. Chemical Formula 1. Wherein each substituent in Formula 1 is as defined in the description of the invention.

A TEMPO-Functionalized Ordered Mesoporous Polymer as a Highly Active and Reusable Organocatalyst

The properties of high stability, periodic porosity, and tunable nature of ordered mesoporous polymers make these materials ideal catalytic nanoreactors. However, their application in organocatalysis has been rarely explored. We report herein for the first time the incorporation of a versatile organocatalyst, 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO), into the pores of an FDU-type mesoporous polymer via a pore surface engineering strategy. The resulting FDU-15-TEMPO possesses a highly ordered mesoporous organic framework and enhanced stability, and shows excellent catalytic activity in the selective oxidation of alcohols and aerobic oxidative synthesis of 2-substituted benzoxazoles, benzimidazoles and benzothiazoles. Moreover, the catalyst can be easily recovered and reused for up to 7 consecutive cycles.

Dowex 50W: A green mild reusable catalyst for the synthesis of 2-aryl benzoxazole derivatives in aqueous medium

In this work simple efficient, one pot and environmentally friendly method was developed for the synthesis of 2-Aryl-1H-benzoxazole derivatives at 80oC using ortho-aminophenol and various aldehydes. It has been found that Dowex 50W is an effective catalyst to prepare moderate to high yield of a variety of benzoxazole derivatives through a clean and simple process. Aqueous medium, green methodology, rapid reaction, reusability of heterogeneous catalyst are the great advantages of this protocol.