316821-53-1

Basic information

• Product Name: 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime
• Synonyms: 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime
• CAS NO: 316821-53-1
• Molecular Weight: 276.143
• Mol File: 316821-53-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime(316821-53-1)
• EPA Substance Registry System: 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime(316821-53-1)

Safety Data

• Hazardous Substances Data: 316821-53-1(Hazardous Substances Data)

Upstream product

• 15754-20-8 (E)-acetophenone O-methyloxime 
• 111-42-2 2,2'-iminobis[ethanol] 
• 281681-22-9 (E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)propiophenone O-methyloxime 

Downstream Products

• 281681-23-0 1-acetoxy-3-acetylamino-3-phenylpropane 
• 281681-20-7 3-[(4R,5R)-4,5-Bis(1-methoxycyclopentyl)-1,3,2-dioxoborolan-2-yl]propiophenone O-methyloxime 
• 281681-21-8 3-[(4S,5S)-4,5-Bis(1-methoxycyclopentyl)-1,3,2-dioxoborolan-2-yl]propiophenone O-methyloxime 

Relevant articles and documents

'Transmitted' remote double diastereoselection effects on the asymmetric reduction of β-boronate oxime ethers

Remote asymmetric induction in the reduction of a homochiral β-boronate oxime ether to the corresponding amine failed to provide asymmetric induction with a chiral reducing agents, but use of a chiral reducing agent produced extreme double diastereoselection effects which show that remote asymmetry can be 'transmitted' by suitable choice of a 'partner' molecule. (C) 2000 Published by Elsevier Science Ltd.