31895-21-3 Usage
Description
Thiocyclam, also known as Thiocyclam oxalate, is an organosulfur heterocyclic compound derived from the natural toxin nereistoxin. It is characterized by its 1,2,3-trithiane structure with a dimethylamino group replacing one of the hydrogens at position 5. Thiocyclam acts as a nicotinic acetylcholine receptor agonist and was historically used as a broad-spectrum insecticide. However, it is also toxic to bees, fish, and other aquatic organisms, leading to its disapproval for use within the European Union.
Uses
Used in Pest Control Industry:
Thiocyclam is used as a pro-insecticide for its rapid conversion into the active compound nereistoxin in biological media. It exhibits limited systemic activity with stomach and contact action, causing paralysis through ganglionic blocking action on the insect central nervous system. Thiocyclam is primarily used as the hydrogen oxalate salt, which is then converted into the active nereistoxin and its oxide in soils and plants, ultimately breaking down into smaller molecules. This application is particularly effective against a broad spectrum of insects, making it a valuable tool in pest control. However, its use is restricted due to its toxicity to non-target organisms such as bees, fish, and other aquatic life.
Check Digit Verification of cas no
The CAS Registry Mumber 31895-21-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,8,9 and 5 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 31895-21:
(7*3)+(6*1)+(5*8)+(4*9)+(3*5)+(2*2)+(1*1)=123
123 % 10 = 3
So 31895-21-3 is a valid CAS Registry Number.
InChI:InChI=1/C5H11NS3/c1-6(2)5-3-7-9-8-4-5/h5H,3-4H2,1-2H3
31895-21-3Relevant articles and documents
A New Group of Compounds Derived from Nereistoxin - Synthesis of Bis-dimethylamino-tris-disulfanes
Muehlstaedt, M.,Heinicke, J.,Schubert H.
, p. 841 - 847 (2007/10/02)
The reaction of organo-thiosulfates, BUNTE-salts, with mercaptans is a convenient synthesis of disulfanes.Similarly bis-BUNTE-salt 7 and tert. butyl mercaptan give bis-disulfane 5c.By treating 7 with several aliphatic mercaptans we found the formation of the tris-disulfanes 8a-d in preparative amounts in addition to the bis-disulfanes 5a-d expected.This reaction was investigated.The preparation of the compounds 8 is described and a proposal is given for a mechanism of the formation of 8 as a thiol-disulfide-interchange.