321887-10-9

Basic information

• Product Name: (2S,3S,4aR,8S,8aS)-2,3-Dimethoxy-2,3-dimethyl-8-(4-nitro-benzoyloxy)-2,3,4a,5,8,8a-hexahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester
• Synonyms: (2S,3S,4aR,8S,8aS)-2,3-Dimethoxy-2,3-dimethyl-8-(4-nitro-benzoyloxy)-2,3,4a,5,8,8a-hexahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester
• CAS NO: 321887-10-9
• Molecular Weight: 451.43
• Mol File: 321887-10-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S,4aR,8S,8aS)-2,3-Dimethoxy-2,3-dimethyl-8-(4-nitro-benzoyloxy)-2,3,4a,5,8,8a-hexahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4aR,8S,8aS)-2,3-Dimethoxy-2,3-dimethyl-8-(4-nitro-benzoyloxy)-2,3,4a,5,8,8a-hexahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester(321887-10-9)
• EPA Substance Registry System: (2S,3S,4aR,8S,8aS)-2,3-Dimethoxy-2,3-dimethyl-8-(4-nitro-benzoyloxy)-2,3,4a,5,8,8a-hexahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester(321887-10-9)

Safety Data

• Hazardous Substances Data: 321887-10-9(Hazardous Substances Data)

Upstream product

• 245054-32-4 methyl (3R,4S,5R)-3-hydroxy-4,5-<(2S,3S)-2,3-dimethoxybutan-2,3-dioxy>-cyclohex-1-en-1-carboxylate 
• 62-23-7 4-nitro-benzoic acid 
• 40983-58-2 methyl shikimate 
• 138-59-0 shikimic acid 

Downstream Products

• 171963-38-5 methyl [3S-(3α,4β,5α)]-3,4,5-trihydroxy-1-cyclohexene-1-carboxylate 
• 943032-41-5 ((2S,3S,4aR,8S,8aR)-8-(benzyloxy)-2,3-dimethoxy-2,3-dimethyl-2,3,4a,5,8,8a-hexahydrobenzo[b][1,4]dioxin-6-yl)methyl benzoate 

Relevant articles and documents

Efficient synthesis of (-)-methyl 3-epi-shikimate and methyl 3-epi-quinate by one-pot selective protection of trans-1,2-diols

trans-1,2-Diol protections of shikimic and quinic acids have been achieved by in situ formation of the protecting group (2,2,3,3-tetramethoxybutane). The synthetic utility of the protected derivatives is demonstrated by the preparation of (-)-methyl 3-epi