32298-40-1Relevant articles and documents
Aggregation-induced emission and self-assembly of functional tetraphenylethene-based tetracationic dicyclophanes for selective detection of ATP in water
Qin, Chunyan,Li, Yawen,Li, Qingfang,Yan, Chaochao,Cao, Liping
, p. 3531 - 3534 (2021)
Functional dicyclophanes with various substituents (e.g., NO2, Br, OCH3 and OH) were synthesized via one-pot SN2 reaction. Dicyclophanes can form nanospheres via the head-to-tail self-assembly between the cavities and the
Tetrastyryl-based cationic fluorescent probe and preparation method and application thereof
-
Paragraph 0043-0052; 0063-0069; 0078-0084; 0093-0122, (2020/05/30)
The invention discloses a tetrastyryl-based cationic fluorescent probe and a preparation method and application thereof. The method comprises the following steps: preparing a solid compound 1; preparing a faint yellow solid compound 2; preparing a yellow
Tetraarylethylenes from Diarylmethanones and Hexachlorodisilane: The “Sila-McMurry” Reaction
Moxter, Maximilian,Tillmann, Jan,Füser, Matthias,Bolte, Michael,Lerner, Hans-Wolfram,Wagner, Matthias
supporting information, p. 16028 - 16031 (2016/10/26)
Hexachlorodisilane reacts with diarylmethanones (aryl=C6H5, 4-MeC6H4, 4-tBuC6H4, 4-ClC6H4, 4-BrC6H4) to furnish the corresponding tetraarylethylenes in good yields. The reductive conversion requires temperatures of about 160 °C and reaction times of 60–72 h. In the initial step, the Lewis-basic carbonyl groups likely generate low-valent [SiCl2] as an analogue of [TiCl2] in the classical McMurry reaction. The coupling sequence further proceeds via benzopinacolones, which have been isolated as key intermediates.