325683-71-4

Basic information

• Product Name: 3-(diphenylphosphinoyl)propionic acid benzyl ester
• Synonyms: 3-(diphenylphosphinoyl)propionic acid benzyl ester
• CAS NO: 325683-71-4
• Molecular Weight: 364.381
• Mol File: 325683-71-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(diphenylphosphinoyl)propionic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(diphenylphosphinoyl)propionic acid benzyl ester(325683-71-4)
• EPA Substance Registry System: 3-(diphenylphosphinoyl)propionic acid benzyl ester(325683-71-4)

Safety Data

• Hazardous Substances Data: 325683-71-4(Hazardous Substances Data)

Upstream product

• 29874-10-0 3-(diphenyl-phosphinoyl)-propionic acid 
• 234766-61-1 3-(diphenylphosphinoyl)propionyl chloride 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Phosphino carboxylic acid ester functionalized carbosilane dendrimers: Nanoscale ligands for the Pd-catalyzed hydrovinylation reaction in a membrane reactor

Phosphino carboxylic acid ester terminated G0 compounds Si{(CH2)3SiMe2(C6H4 CH2OC(O)(CH2)nCH2PPh2} 4 (9a and 9b; n = 1, 2) and the carbosilane dendrimers Si{(CH2)3 Si((CH2)3SiMe2(C6H4 CH2OC(O)(CH2)nCH2PPh2) 3}4 (10a and 19b; n = 1, 2) have been prepared as hemilabile nanoscale ligands for the palladium-catalyzed codimerization of olefins. The hydrovinylation of styrene was carried out in a continuously operated nanofiltration membrane reactor. Under continuous conditions, the selectivity of the reaction is increased considerably. Monomeric model complexes and the dendritic catalysts were compared for their activity and selectivity in batch reactions. The Pd catalyst complexes were prepared in situ from the dendritic ligands and an (allyl)palladium(II) precursor.