32653-33-1

Basic information

• Product Name: Hexanoic acid, 2-chloro-, (2S)-
• Synonyms: Hexanoic acid, 2-chloro-, (2S)-
• CAS NO: 32653-33-1
• Molecular Formula: C6H11ClO2
• Molecular Weight: 150.60334
• Mol File: 32653-33-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Hexanoic acid, 2-chloro-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanoic acid, 2-chloro-, (2S)-(32653-33-1)
• EPA Substance Registry System: Hexanoic acid, 2-chloro-, (2S)-(32653-33-1)

Safety Data

• Hazardous Substances Data: 32653-33-1(Hazardous Substances Data)

Upstream product

• 142-62-1 hexanoic acid 
• 59045-37-3 1,2;5,6-di-O-(1-methylethylidene)-α-D-glucofuranosyl hexanoate 
• 167937-29-3 1,2;5,6-di-O-(1-methylethylidene)-α-D-glucofuranosyl-2-chloro hexanoate 
• 327-56-0 L-(+)-norleucine 
• 55682-98-9 (+/-)-3-Chloro-1-heptene 

Relevant articles and documents

Asymmetric Synthesis of 2-Chloro- and 2-Bromo-alkanoic acids by Halogenation of α-D-Glucofuranose-Derived Silyl Ketene Acetals.

Optically active (S)-2-bromo- and 2-chloro-alkanoic acids 6 and 7 have been obtained via the diastereoselective halogenation of chiral silyl ketene acetals 3a-f, and subsequent saponification of the resulting crude esters.Examples characterized by e.e. values up to 95percent are reported.The diastereoface selectivity is independent of the silyl ketene acetal E/Z configuration.

Asymmetric Transformation of 2-Phenyl- and 2-Chloroalkanoic Acids via Chiral Oxazolines

Asymmetric transformation of racemic 2-phenyl- and 2-chloroalkanoic acids via oxazolines into the corresponding optically active acids was investigated using (S)-phenylalaninol as a chiral auxiliary.The asymmetric transformation was performed by metalatio