32792-53-3

Basic information

• Product Name: Benzoic acid, 4-chloro-, 4-cyanophenyl ester
• CAS NO: 32792-53-3
• Molecular Formula: C14H8ClNO2
• Molecular Weight: 257.676
• Mol File: 32792-53-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-chloro-, 4-cyanophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-chloro-, 4-cyanophenyl ester(32792-53-3)
• EPA Substance Registry System: Benzoic acid, 4-chloro-, 4-cyanophenyl ester(32792-53-3)

Safety Data

• Hazardous Substances Data: 32792-53-3(Hazardous Substances Data)

Upstream product

• 3058-39-7 4-iodobenzonitrile 
• 74-11-3 para-chlorobenzoic acid 
• 623-00-7 4-bromobenzenecarbonitrile 
• 6310-31-2 S-(p-chlorophenyl) p-chlorobenzenecarbothioate 
• 874-90-8 4-methoxybenzonitrile 
• 104-88-1 4-chlorobenzaldehyde 
• 126747-14-6 4-cyanophenylboronic acid 
• 767-00-0 4-cyanophenol 
• 122-01-0 4-chloro-benzoyl chloride 
• 10364-95-1 1-(4-chloro-benzoyl)-1H-imidazole 

Downstream Products

• 5410-99-1 4-methoxyphenyl 4-chlorobenzoate 
• 1336943-54-4 1-benzoyl-4-(4-cyanophenoxy)-2,3,5,6-tetrafluorobenzene 
• 456-21-3 4-chlorobenzoyl fluoride 

Relevant articles and documents

Dual aminoquinolate diarylboron and nickel catalysed metallaphotoredox platform for carbon-oxygen bond construction

Herein, aminoquinolate diarylboron complexes are utilized as photocatalysts in dual Ni/photoredox catalyzed carbon-oxygen construction reactions. Via this unified metallaphotoredox platform, diverse (hetero)aryl halides can be conveniently coupled with acids, alcohols and water. This method features operational simplicity, broad substrate scope and good compatibility with functional groups. This journal is

Rhodium-catalyzed cleavage reaction of aryl methyl ethers with thioesters

A rhodium complex catalyzed the reaction of aryl methyl ethers and thioesters giving the corresponding aryl esters and methyl sulfides. S-(p-Chlorophenyl) p-(dimethylamino)benzothioate was used for the reaction of methyl aryl ethers with electron-withdrawing groups, and an S-(p-tolyl) derivative was used for those with electron-donating groups. Polymethoxybenzenes were converted to the esters in a regioselective manner.

Activation of imidazolides using methyl trifluoromethanesulfonate: A convenient method for the preparation of hindered esters and amides

Treatment of imidazolides with methyl trifluoromethanesulfonate followed by reaction with alcohols or amines provides a convenient one-pot procedure for the preparation of esters and amides. The method is applicable to imidazolides of low reactivity as well as to hindered nucleophiles.