329041-72-7

Basic information

• Product Name: 4-Vinylpyridine-d3, 97 atom % D (Inhibited with 0.1% tert-Butylcatechol)
• Synonyms: 4-Vinylpyridine-d3, 97 atom % D (Inhibited with 0.1% tert-Butylcatechol)
• CAS NO: 329041-72-7
• Molecular Weight: 0
• Mol File: 329041-72-7.mol
• Article Data: 30

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Vinylpyridine-d3, 97 atom % D (Inhibited with 0.1% tert-Butylcatechol)(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Vinylpyridine-d3, 97 atom % D (Inhibited with 0.1% tert-Butylcatechol)(329041-72-7)
• EPA Substance Registry System: 4-Vinylpyridine-d3, 97 atom % D (Inhibited with 0.1% tert-Butylcatechol)(329041-72-7)

Safety Data

• Hazardous Substances Data: 329041-72-7(Hazardous Substances Data)

Upstream product

• 108-89-4 picoline 
• 50-00-0 formaldehyd 
• 64-17-5 ethanol 
• 67-56-1 methanol 
• 34064-35-2 4-(oxiran-2-yl)pyridine 
• 400759-02-6 N-[2-(4-pyridyl)ethyl]quinuclidinium 
• 82769-08-2 poly{Ru(2,2'-bipyridine)2(4-vinylpyridine)2}⁽²⁺⁾ 
• 16887-00-6 chloride 
• 872-85-5 pyridine-4-carbaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 2510-22-7 4-pyridylacetylene 
• 15854-87-2 4-iodopyridine 
• 133810-35-2 4-(2-(trimethylsilyl)ethynyl)pyridine 
• 2629-72-3 4-(3-Hydroxypropyl)pyridine 

Downstream Products

• 16571-49-6 3-(2-pyridin-4-yl-ethyl)-indole 
• 30456-60-1 4-(2-methyl-cyclohex-3-enyl)-pyridine 
• 84200-06-6 3-(pyridin-4-yl)propanenitrile 
• 112351-30-1 N-benzyl-N-(2-[4]pyridyl-ethyl)-aniline 
• 110145-49-8 6-phenyl-3-(2-pyridin-4-yl-ethyl)-benzo[e][1,3]oxazine-2,4-dione 
• 741201-50-3 N-[4-(2-pyridin-4-yl-ethanesulfonyl)-phenyl]-acetamide 
• 109090-42-8 2-propoxy-N-(2-[4]pyridyl-ethyl)-aniline 
• 65003-03-4 4-(2-(phenylsulfonyl)ethyl)pyridine 
• 28487-17-4 2-(4-Pyridylethyl)-cyclohexanon 
• 102552-31-8 2,2-bis-(2-[4]pyridyl-ethyl)-cyclohexanone 
• 109688-68-8 N-(2-[4]pyridyl-ethyl)-o-anisidine 
• 27031-36-3 N-(2-[4]pyridyl-ethyl)-p-toluidine 
• 99516-20-8 ethyl-(2-[4]pyridyl-ethyl)-amine 
• 112948-79-5 4-[4]pyridyl-1-p-tolyl-butan-1-one 

Relevant articles and documents

Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation

We report a Rh-catalyst for accessing olefins from primary alcohols by a C-C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N,N-dimethylacrylamide as a sacrificial acceptor of hydrogen gas. Alcohols with diverse functionality and structure undergo oxidative dehydroxymethylation to access the corresponding olefins. Our catalyst protocol enables a two-step semisynthesis of (+)-yohimbenone and dehomologation of feedstock olefins.

KO-t-Bu Catalyzed Thiolation of β-(Hetero)arylethyl Ethers via MeOH Elimination/hydrothiolation

Herein, we describe a KO-t-Bu catalyzed thiolation of β-(hetero)arylethyl ethers through MeOH elimination to form (hetero)arylalkenes followed by anti-Markovnikov hydrothiolation to afford linear thioethers. The system works well with a variety of β-(hetero)arylethyl ethers, including electron-deficient, electron-neutral, electron-rich, and branched substrates and a range of aliphatic and aromatic thiols.

Design and characterization of a heterocyclic electrophilic fragment library for the discovery of cysteine-targeted covalent inhibitors

A fragment library of electrophilic small heterocycles was characterized through cysteine-reactivity and aqueous stability tests that suggested their potential as covalent warheads. The analysis of theoretical and experimental descriptors revealed correlations between the electronic properties of the heterocyclic cores and their reactivity against GSH that are helpful in identifying suitable fragments for cysteines with specific nucleophilicity. The most important advantage of these fragments is that they show only minimal structural differences from non-electrophilic counterparts. Therefore, they could be used effectively in the design of targeted covalent inhibitors with minimal influence on key non-covalent interactions.