329329-57-9

Basic information

• Product Name: 2-Propenoic acid, 2-(bromomethyl)-3-(4-methylphenyl)-, ethyl ester, (2Z)-
• CAS NO: 329329-57-9
• Molecular Formula: C13H15BrO2
• Molecular Weight: 283.165
• Mol File: 329329-57-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-(bromomethyl)-3-(4-methylphenyl)-, ethyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-(bromomethyl)-3-(4-methylphenyl)-, ethyl ester, (2Z)-(329329-57-9)
• EPA Substance Registry System: 2-Propenoic acid, 2-(bromomethyl)-3-(4-methylphenyl)-, ethyl ester, (2Z)-(329329-57-9)

Safety Data

• Hazardous Substances Data: 329329-57-9(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 140-88-5 ethyl acrylate 
• 145316-15-0 ethyl 2-(hydroxy(p-tolyl)methyl)acrylate 

Downstream Products

• 1527470-80-9 (Z)-ethyl 2-((4-benzhydrylpiperazin-1-yl)methyl)-3-p-tolylacrylate 
• 847653-82-1 ethyl 2-methylene-3-(4-tolyl)pentanoate 

Relevant articles and documents

Efficient synthesis of N-allylated 2-nitroiminoimidazolidine analogues from Baylis–Hillman bromides

Various Baylis–Hillman–derived new N-allylated 2-nitroiminoimidazolidine analogs were efficiently prepared using potassium carbonate as base. Simple workup procedure, excellent yields, and mild reaction conditions are the salient features of this method. All the synthesized compounds are screened for their larvicidal activity on fourth instar mosquito larvae, Culex quinquefasciatus.

Expedient synthesis of β,β-disubstituted α- methylenepropionates

Baylis-Hillman alcohols are excellent sources of the allylic halides ArCHCH(CH2X)(CO2R) (X=Br, Cl; R1=Me, Et, But). The Z double bond isomers are attained in high isomeric purity (>14:1, Z/E). The halides are ch