3299-05-6Relevant articles and documents
Bonner
, p. 183 (1947)
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Eliel,Rerick
, p. 1088 (1958)
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Auto-Tandem Catalysis with Frustrated Lewis Pairs for Reductive Etherification of Aldehydes and Ketones
Bakos, Mária,Gy?m?re, ádám,Domján, Attila,Soós, Tibor
supporting information, p. 5217 - 5221 (2017/04/27)
Herein we report that a single frustrated Lewis pair (FLP) catalyst can promote the reductive etherification of aldehydes and ketones. The reaction does not require an exogenous acid catalyst, but the combined action of FLP on H2, R-OH or H2O generates the required Br?nsted acid in a reversible, “turn on” manner. The method is not only a complementary metal-free reductive etherification, but also a niche procedure for ethers that would be either synthetically inconvenient or even intractable to access by alternative synthetic protocols.
Direct and efficient synthesis of unsymmetrical ethers from alcohols catalyzed by Fe(HSO4)3 under solvent-free conditions
Moghadam, Bashir Nazari,Akhlaghinia, Batool,Rezazadeh, Soodabeh
, p. 1487 - 1501 (2016/04/26)
Highly efficient Fe(HSO4)3 catalyzed etherification of primary, secondary and tertiary benzylic alcohols with primary and secondary aliphatic alcohols is reported. The reaction affords unsymmetrical benzyl ethers in good to excellent yields under solvent-free conditions.