33204-48-7Relevant articles and documents
High iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes
Iu, Leo,Fuentes, José A.,Janka, Mesfin E.,Fontenot, Kevin J.,Clarke, Matthew L.
supporting information, p. 2120 - 2124 (2019/01/25)
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
Synthesis of New Chiral Phosphinephosphites Having 2-Diphenylphosphinobiphenyl-2'-yl Backbone and Their Use in Rh(I)-Catalyzed Asymmetric Hydroformylations
Higashizima, Takanori,Sakai, Nozomu,Nozaki, Kyoko,Takaya, Hidemasa
, p. 2023 - 2026 (2007/10/02)
New chiral phosphinephosphites (R)-(5,5'-dichloro-2-diphenylphosphino-4,4',6,6'-tetramethylbiphenyl-2'-yl)(S)-1,1'-binaphthalen-2,2'-diyl)phosphite and its enantiomer (S,R)-BIPHEMPHOS have been synthesized from 5,5'-dichloro-4,4',6,6'-tetramethyl-2,2'-biphenyldiol in enantiomerically pure form.Their Rh(I) complexes have been shown to be highly efficient catalysts for asymmetric hydroformylations of a variety of olefinic substrates.The corresponding phosphinephosphites derived from 2,2'-biphenyldiol were also tested as ligands for asymmetric hydroformylation.
TOTAL SYNTHESIS OF (-)-BETAENONE C
Ichihara, Akitami,Miki, Shokyo,Kawagishi, Hirokazu,Sakamura, Sadao
, p. 4551 - 4554 (2007/10/02)
Stereoselctive synthesis of (-)-betaenone C through intramolecular Diels-Alder reaction has made possible to provide pertinent intermediates for the biosynthetic study of betaenones.