333796-97-7Relevant articles and documents
A stereoselective approach to optically active bifunctional 1,3-dimethyl-1,3-diphenyldisiloxanes
Oishi, Motoi,Kawakami, Yusuke
, p. 549 - 551 (1999)
(Matrix presented) Functionalized disiloxanes have attracted much attention as versatile synthetic intermediates in the preparation of disiloxane-containing polymers. In this report, a highly stereoselective (98% inversion) halogenating cleavage reaction of the silicon-naphthyl bond to obtain optically active (S,S)-1,3-dimethyl-1,3-diphenyldisiloxanediol ((S,S):(R,S):(R,R) = 86:14:0) was demonstrated.
