334917-69-0Relevant articles and documents
Short syntheses of gabosine I and gabosine G from δ-D-gluconolactone
Shing, Tony K. M.,Cheng, Hau M.
, p. 6610 - 6613 (2007)
(Chemical Equation Presented) A short synthesis of gabosine I (1) from δ-D-gluconolactone (3) in four steps, involving a one-pot TPAP oxidation-K2-CO3-mediated intramolecular Horner-Wadsworth-Emmons (HWE) olefination as the key step,
Baylis-Hillman reaction based flexible strategy for the synthesis of gabosine I, gabosine G, epi-gabosine i and carba l-pentose
Radha Krishna, Palakodety,Kadiyala, Raghu Ram
scheme or table, p. 744 - 747 (2012/03/08)
A combination of diastereoselective Baylis-Hillman reaction and RCM reaction set is used as the flexible strategy for the ready access to cyclohexenoid and cyclopentenoid skeletons.
Short and efficient syntheses of gabosine I, streptol, 7-O-acetylstreptol, 1-epi-streptol, gabosine K, and carba α-d-glucose from δ-d-gluconolactone
Shing, Tony K. M.,Chen,Ng
, p. 1318 - 1320 (2011/08/03)
δ-d-Gluconolactone was carbocyclized into an EOM-protected cyclohexenone in four steps involving perethoxymethylation, phosphonate anion addition, reduction, and oxidation with concomitant Horner-Wadsworth-Emmons alkenation. The stable key enone was effic