3360-54-1

Basic information

• Product Name: (1-BROMOMETHYL-VINYL)-BENZENE
• Synonyms: (1-BROMOMETHYL-VINYL)-BENZENE;(3-BroMoprop-1-en-2-yl)benzene
• CAS NO: 3360-54-1
• Molecular Formula: C₉H₉Br
• Molecular Weight: 197.07176
• Mol File: 3360-54-1.mol
• Article Data: 118

Chemical Properties

• Melting Point: 29 °C(Solv: ethanol (64-17-5))
• Boiling Point: 230.9°C at 760 mmHg
• Flash Point: 99.7°C
• Appearance: /
• Density: 1.327g/cm³
• Vapor Pressure: 0.0973mmHg at 25°C
• Refractive Index: 1.562
• CAS DataBase Reference: (1-BROMOMETHYL-VINYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: (1-BROMOMETHYL-VINYL)-BENZENE(3360-54-1)
• EPA Substance Registry System: (1-BROMOMETHYL-VINYL)-BENZENE(3360-54-1)

Safety Data

• Hazardous Substances Data: 3360-54-1(Hazardous Substances Data)

Usage

General Description

(1-Bromomethyl-vinyl)-benzene, also known as styrene bromomethyl vinylbenzene or 1-phenyl-2-bromoethene, is a chemical compound with the molecular formula C9H9Br. It is a colorless to yellow liquid with a strong, sweet odor that is used in the production of various polymers and plastics such as polystyrene, synthetic rubber, and latex. It is also used as a precursor for the synthesis of other organic compounds and as a chemical intermediate in the manufacturing of adhesives, coatings, and resins. Additionally, (1-Bromomethyl-vinyl)-benzene is also used in the production of styrene-butadiene rubber and as a stabilizer for PVC (polyvinyl chloride) resins. However, it is important to handle this compound with caution as it is considered to be a hazardous chemical with potential health and environmental risks.

InChI:InChI=1/C9H9Br/c1-8(7-10)9-5-3-2-4-6-9/h2-6H,1,7H2

Upstream product

• 98-83-9 isopropenylbenzene 
• 108-86-1 bromobenzene 
• 91083-18-0 (η5-C5H5)Ru(η3-2-phenylallyl)Br2 
• 122-78-1 phenylacetaldehyde 
• 98-82-8 Isopropylbenzene 
• 4432-63-7 2-phenylacrolein 
• 2439-85-2 N-bromophthalimide 
• 3575-19-7 2-bromo-2-phenylpropane 
• 31778-29-7 1-bromo-2-phenylpropan-2-ol 
• 6006-81-1 3-hydroxy-2-phenylpropene 
• 437709-29-0 1-phenylcyclopropyl methanesulfonate 
• 70-11-1 α-bromoacetophenone 
• 36043-44-4 (1,2-dibromopropan-2-yl)benzene 
• 98-86-2 acetophenone 

Downstream Products

• 16606-47-6 2,4-diphenylbut-1-ene 
• 123078-75-1 (3-(allyloxy)prop-1-en-2-yl)benzene 
• 843651-73-0 N-tert-butoxycarbonyl-N'-(2-phenylallyl)hydrazine 
• 753452-20-9 N-(1-allyl-but-3-enyl)-N-(2-phenyl-allyl)-acrylamide 
• 63942-88-1 (5-methylhexa-1,5-dien-2-yl)benzene 
• 51758-24-8 4-phenyl-4-penten-1-al 
• 51876-00-7 1-diethoxyphosphonyl-2-phenylprop-2-ene 
• 835879-85-1 methyl 2-(hydroxymethyl)-4-phenylpent-4-enoate 
• 769196-54-5 (S)-3-phenyl-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 669694-91-1 N-(2-nitrophenyl)-N-(2-phenyl-2-propenyl)acetamide 
• 678194-47-3 2-(hydroxymethyl)-4-phenylpent-4-enoic acid 
• 405517-46-6 (2R,3S)-3-Hydroxy-2-phenyl-3-(2-phenyl-allyl)-piperidine-1-carboxylic acid tert-butyl ester 

Relevant articles and documents

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Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Electrochemical-induced radical allylation via the fragmentation of alkyl 1,4-dihydropyridines

Aldehydes are abundant chemical motifs presented in natural products and pharmaceuticals. As a radical precursor, its application is limited. Dihydropyridines (DHPs) can act as masked aldehydes, providing alkyl radicals under the activation of Lewis acid, heat, SET oxidant and light irradiation. Herein, we report the direct activation of 4-alkyl DHPs via single electron transfer at the anode. C–C bond homolysis at the C4-position of DHP generated the corresponding alkyl radical, which was captured subsequently by 2-phenyl and 2-ethoxy carbonyl allyl bromide. The following intramolecular elimination reaction afforded 20 different radical allylation products bearing various alkyl substituents with yields up to 92%.

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method includes the steps of: (A) providing a compound (I) with an unsaturated double bond, a trifluoromethyl-containing reagent, and a catalyst; wherein, the catalyst is represented by Formula (II): M(O)mL1yL2z??(II);wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and(B) mixing the compound with an unsaturated double bond and the trifluoromethyl-containing reagent to perform an oxidative cleavage of the compound with the unsaturated double bond by using the catalyst in air or under oxygen atmosphere condition to obtain a compound represented by Formula (III):