3383-05-9Relevant articles and documents
Suzuki-Miyaura Csp2-Csp2Cross-Couplings Employing Nickel(II) Pincer Precatalysts: Mechanistic Investigations
Ho, Curtis C.,Olding, Angus,Fuller, Rebecca O.,Canty, Allan J.,Lucas, Nigel T.,Bissember, Alex C.
supporting information, p. 2305 - 2310 (2021/05/06)
This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.
Sequential Two-Fold Claisen Rearrangement, One-Pot Ring-Closing Metathesis and Cross-Metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives
Mandal, Shyamasankar,Banerjee, Jeet,Maity, Sougata,Chattopadhyay, Shital K.
, (2021/02/26)
A synthetic protocol involving sequential use of three atom-economic processes viz. Claisen rearrangement, ring-closing metathesis and cross metathesis has been developed to access 7-substituted benzo[b]azepine and benzo[b]oxepine derivatives starting from appropriate aniline or phenol in good overall yield. A one-pot RCM-CM protocol has also been developed for the synthesis of benzazepine and benzoxepine derivatives.
Epoxy (meth) acrylate compounds and pharmaceutical compositions containing curable composition
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Paragraph 0091-0094, (2019/04/17)
[Problem] To provide an epoxy (meth)acrylate compound that serves as a material for a protective film that is unlikely to cause migration to an electrically conductive pattern, and a curable composition containing the epoxy (meth)acrylate compound. [Solut