339588-24-8

Basic information

• Product Name: 1-[6-hexylsulfonyl chloride]-N-(benzyl)methyldisulfonimide
• Synonyms: 1-[6-hexylsulfonyl chloride]-N-(benzyl)methyldisulfonimide
• CAS NO: 339588-24-8
• Molecular Weight: 431.983
• Mol File: 339588-24-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[6-hexylsulfonyl chloride]-N-(benzyl)methyldisulfonimide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[6-hexylsulfonyl chloride]-N-(benzyl)methyldisulfonimide(339588-24-8)
• EPA Substance Registry System: 1-[6-hexylsulfonyl chloride]-N-(benzyl)methyldisulfonimide(339588-24-8)

Safety Data

• Hazardous Substances Data: 339588-24-8(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 109203-08-9 1,6-hexanedisulfonic acid disodium salt 
• 629-03-8 1 ,6-dibromohexane 

Downstream Products

• 339588-29-3 1-[1-(6-hexylsulfonyl chloride)-6-hexyl-N-(benzyl)hexyldisulfonimide]-N-benzylhexyldimethylsulfonimide 
• 339588-28-2 1-[6-hexyl-N-(benzyl)sulfonamide]-N-(benzyl)methyldisulfonimide 

Relevant articles and documents

Synthesis and reactivity of polydisulfonimides

The first synthesis of alkyl disulfonimide oligomers is presented. In the process of synthesizing these oligomers, previously unreported reactivity of the N-substituted disulfonimide functional group was discovered. Under basic conditions, unexpected lengthening of the oligomers occurs through a "transdisulfonimidation" reaction, whereby new disulfonimides are synthesized from existing ones by reaction with sulfonamide anion. This process appears to proceed via formation of a sulfene intermediate. Support for the E1cBRev mechanism includes isotope scrambling, substituent effects, and sulfene trapping.