34143-95-8Relevant articles and documents
Synthetic Photochemistry. XXI. The Sensitized Photooxygenation of Calarene. A Facile Hock Cleavage of an Allylhydroperoxide and Structure Revision for Aristolenols
Takeshita, Hitoshi,Shimooda, Isao,Hatsui, Toshihide
, p. 3721 - 3722 (2007/10/02)
An allylic hydroperoxide formed by the sensitized photooxidation of calarene causes a Hock cleavage.A revised stereochemistry of an aristolenol is given on the basis of the direction of oxygenation.