34414-53-4

Basic information

• Product Name: Benzene, 1,1'-(1-propene-1,3-diyl)bis[4-methoxy-
• CAS NO: 34414-53-4
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol File: 34414-53-4.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-propene-1,3-diyl)bis[4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-propene-1,3-diyl)bis[4-methoxy-(34414-53-4)
• EPA Substance Registry System: Benzene, 1,1'-(1-propene-1,3-diyl)bis[4-methoxy-(34414-53-4)

Safety Data

• Hazardous Substances Data: 34414-53-4(Hazardous Substances Data)

Upstream product

• 13677-46-8 1,3-bis(4-methoxyphenyl)prop-2-en-1-ol 
• 55-21-0 benzamide 
• 768-60-5 4-methoxyphenylacetylen 
• 5720-07-0 4-methoxyphenylboronic acid 
• 53484-54-1 3-(4-methoxyphenyl)prop-2-enyl acetate 
• 696-62-8 para-iodoanisole 
• 140-67-0 Estragole 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 123-11-5 4-methoxy-benzaldehyde 
• 6000-10-8 trans-1,2-bis(4-methoxyphenyl)cyclopropane 
• 702-23-8 2-(4-Methoxyphenyl)ethanol 
• 41564-67-4 (E)-1,3-bis(4-methoxyphenyl)-2-propene-1-one 
• 20615-47-8 1,3-di(4-methoxyphenyl)propan-1-one 
• 637-69-4 4-Methoxystyrene 

Downstream Products

• 4741-73-5 1,3-bis(4-methoxyphenyl)propane 
• 1440747-52-3 (E)-4,4'-(5-phenylpent-1-ene-1,3-diyl)bis(methoxybenzene) 
• 1352732-78-5 (E)-5-(4-methoxystyryl)-1-(4-methoxyphenyl)-1H-tetrazole 
• 1220346-15-5 (E)-4-methylbenzaldehyde O-(E)-1,3-bis(4-methoxyphenyl)allyl oxime 

Relevant articles and documents

Base-promoted one-pot synthesis of pyridine derivatives via aromatic alkyne annulation using benzamides as nitrogen source

In the presence of Cs2CO3, the first simple, efficient, and one-pot procedure for the synthesis of 3,5-diaryl pyridines via a variety of aromatic terminal alkynes with benzamides as the nitrogen source in sulfolane is described. The formation of pyridine derivatives accompanies the outcome of 1,3-diaryl propenes, which are also useful intermediates in organic synthesis. Thus, pyridine ring results from a formal [2+2+1+1] cyclocondensation of three alkynes with benzamides, and one of the alkynes provides one carbon, whilst benzamides provide a nitrogen source only. A new transformation of alkynes as well as new utility of benzamide are found in this work.

Ru-Catalyzed Completely Deoxygenative Coupling of 2-Arylethanols through Base-Induced Net Decarbonylation

Substituted arylethanols can be coupled by using a readily available Ru catalyst in a fully deoxygenative manner to produce hydrocarbon chains in one step. Control experiments indicate that the first deoxygenation occurs through an aldol condensation, whereas the second occurs through a base-induced net decarbonylation. This double deoxygenation enables further development in the use of alcohols as versatile and green alkylating reagents, as well as in other fields, such as deoxygenation and upgrading of overfunctionalized biomass to produce hydrocarbons.

Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes

A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.