34636-83-4

Basic information

• Product Name: p-chlorophenylthio-α,α-bis-p-chlorophenylsulphonyltoluene
• Synonyms: p-chlorophenylthio-α,α-bis-p-chlorophenylsulphonyltoluene
• CAS NO: 34636-83-4
• Molecular Weight: 507.867
• Mol File: 34636-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-chlorophenylthio-α,α-bis-p-chlorophenylsulphonyltoluene(CAS DataBase Reference)
• NIST Chemistry Reference: p-chlorophenylthio-α,α-bis-p-chlorophenylsulphonyltoluene(34636-83-4)
• EPA Substance Registry System: p-chlorophenylthio-α,α-bis-p-chlorophenylsulphonyltoluene(34636-83-4)

Safety Data

• Hazardous Substances Data: 34636-83-4(Hazardous Substances Data)

Upstream product

• 2394-02-7 bis(p-chlorophenylsulfonyl)methane 
• 106-54-7 p-Chlorothiophenol 
• 17241-11-1 trithioorthoformic acid tris-(4-chloro-phenyl ester) 
• 121434-40-0 phenyliodonium bis(p-chlorophenylsulphonyl)methylide 

Relevant articles and documents

REACTIVITY OF PHENYLIODONIUM BIS(ARYLSULPHONYL)METHYLIDES TOWARDS ALKENES AND ALKYNES: CRYSTAL STRUCTURE OF 9-PHENYLSULPHONYL-1,2,3,4,4a,9a-HEXAHYDRO-1,4-METHANOFLUORENE

Thermal or photochemical reactions of phenyliodonium bis(arylsulphonyl)methylides with alkenes lead normally to gem-(arylsulphonyl)cyclopropanes.Norbornene and trans-stilbene, however, afford 1-(phenylsulphonyl)indane derivatives.The crystal structure of the title compound /= 3.0>> confirmed the identity of the product with norbornene.Diarylacetylenes give 1-(arylsulphonyl)indenes.Thermal decomposition of the ylides involves a new rearrangement, with formation of aryl arenethiosulphonates.