35148-19-7

Basic information

• Product Name: TRANS-9-DODECEN-1-YL ACETATE
• Synonyms: acetate,(e)-9-dodecen-1-o;(E)-dodec-9-enyl acetate;TRANS-9-DODECENYL ACETATE;9-DODECENYLACETATE;Acetic acid (E)-9-dodecenyl ester;9E-12Ac;(9E)-9-Dodecenyl acetate;(E)-9-Dodecen-1-ol acetate
• CAS NO: 35148-19-7
• Molecular Formula: C₁₄H₂₆O₂
• Molecular Weight: 226.35504
• EINECS: 252-397-7
• Mol File: 35148-19-7.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 300.1±21.0℃ (760 Torr)
• Flash Point: 96.5±20.4℃
• Appearance: /
• Density: 0.881±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.00114mmHg at 25°C
• Refractive Index: 1.4445 (22℃)
• CAS DataBase Reference: TRANS-9-DODECEN-1-YL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-9-DODECEN-1-YL ACETATE(35148-19-7)
• EPA Substance Registry System: TRANS-9-DODECEN-1-YL ACETATE(35148-19-7)

Safety Data

• Hazardous Substances Data: 35148-19-7(Hazardous Substances Data)

Usage

Uses

(9E)-Dodecen-1-yl Acetate can be used in biological study of identification of the female sex pheromone of the Leafroller Proeulia triquetra Obraztsov (Lepidoptera: Tortricidae).

InChI:InChI=1/C14H26O2/c1-3-4-5-6-7-8-9-10-11-12-13-16-14(2)15/h4-5H,3,6-13H2,1-2H3/b5-4+

Upstream product

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Relevant articles and documents

Pheromones of insects and their analogs. LIV. Synthesis of dodec-9e-en-1-ol and its acetate - Components of the sex pheromone of Sparganothis pilleriana

Using the Claisen rearrangement in the construction of a double bond with the E configuration, we have synthesized dodec-9E-en-1-ol and its acetate, which are components of the sex pheromone of Sparganothis pilleriana.

A chemoselective reduction of alkynes to (E)-alkenes

The trans reduction of all types of alkynes to give (E)-olefins is achieved through a two-stage trans hydrosilylation and protodesilylation. Reaction of an alkyne and a silane with the ruthenium catalyst [Cp*Ru(MeCN)3]PF6 results in

SYNTHESIS OF Z-OLEFIN-CONTAINING LEPIDOPTERAN INSECT PHEROMONES

The present invention is directed to methods of synthesizing insect pheromones, particularly lepidopteran insect pheromones, their precursors and derivatives from inexpensive, readily available starting materials using olefin metathesis catalysis.