354-56-3Relevant articles and documents
Miller et al.
, p. 4992 (1956)
Conversion of 1,1,2-trichlorotrifluoroethane to 1,1,1-trichlorotrifluoroethane and 1,1-dichlorotetrafluoroethane over aluminium-based catalysts
Bozorgzadeh,Kemnitz,Nickkho-Amiry,Skapin,Winfield
, p. 45 - 52 (2007/10/03)
Conversion of CCl2FCClF2 to CCl2FCF3 is achieved in the temperature range, 593-713 K, under flow conditions by using the catalysts, β-AlF3 or γ-alumina, prefluorinated with CCl2F2/sub
REACTIONS OF CHLORINE MONOFLUORIDE. IV. ADDITION OF CHLORINE MONOFLUORIDE TO HALOGEN-SUBSTITUTED ALKENES
Boguslavskaya, L. S.,Chuvatkin, N. N.,Panteleeva, I. Yu.
, p. 1832 - 1842 (2007/10/02)
The reactions of chlorine monofluoride with halogenoethylenes (1,1-dichloro-, 1,2-dichloro-, trichloro-, and tetrachloroethylenes) and halogenopropenes ( 3-bromo-, 3,3,3-trichloro-, E- and Z-1,3-dichloro-, 3-chloro-2-methyl-, and perfluoropropenes) were investigated in inert solvents in the presence of ethyl acetate as external nucleophile.In all cases chloroacyloxy adducts were isolated and identified in addition to the chlorofluorination products, and this indicates an electrophilic mechanism for the chlorofluorination of polyhalogenoalkenes.Methyl chloromaleate, chlorofumarate, chlorofluoroethylenedicarboxylate, α,β-difluoroacrylate, and perfluoromethacrylate in anhydrous hydrogen fluoride form the corresponding chlorofluoro adducts with satisfactory yields, whereas the reaction takes place with difficulty in inert solvents.